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Updated: Jun 6, 2025

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Published on: April 9, 2018

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部分硫酸柱[5]领域:合成和分子识别特性

Ayona Goswami1, Süleyman Selim Çınaroğlu2, Noor Singh1

  • 1Department of Chemistry and Biochemistry, University of Maryland, College Park, College Park, Maryland, 20742, United States.

Chemistry (Weinheim an der Bergstrasse, Germany)
|November 30, 2024
PubMed
概括

我们合成了具有不同硫酸盐组的硫酸盐柱[5]. 增加硫酸盐含量提高了水溶性和宿主-客体结合亲和力,用于超分子化学中的应用.

关键词:
静电相互作用 静电相互作用异热量定位热量计 异热量定位热量计柱状二烯硫酸盐 柱状二烯硫酸盐超直结合性 超直结合性在X射线晶体学研究中,

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Preparation and Reactions of Sulfides

Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
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