定制聚乙烯的介电性质和尺寸稳定性 (Poly(Phenylene Ether) 使用双胺交叉连接器用于高频PCB应用
Yejun Ban1, Jihun Lee2, Hyunseong Shin2
1Electronic Convergence Materials & Device Research Center, Korea Electronics Technology Institute, Seongnam, Gyeonggi, 13509, Republic of Korea.
Macromolecular rapid communications
|November 30, 2024
概括
新的聚乙烯乙-双胺树脂为6G通信提供了卓越的介电性质和稳定性. 这些先进的材料减少了热膨胀,并在恶劣条件下保持性能,非常适合高频印刷电路板.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 电气工程 电气工程
背景情况:
- 6G通信时代要求印刷电路板 (PCB) 的先进介电基板材料具有低介电常数 (Dk),低介电损失 (Df) 和高维稳定性.
- 现有的材料往往难以满足这些严格的要求,特别是在高频率下.
研究的目的:
- 开发具有增强介电性质和尺寸稳定性的新型聚乙烯乙-双胺 (PPE-BMI) 树脂.
- 为了研究不同 bismaleimide (BMI) 交叉连接剂含量对材料性能的影响.
- 阐明管理改进特征的结构-属性关系.
主要方法:
- 合成具有控制BMI含量的PPE-BMI树脂.
- 在100 GHz以上的频率上测量介电性质.
- 在85°C/85%相对湿度下进行可靠性测试.
- 测量热膨胀系数的方法.
- 分子动力学模拟用于分析自由体积,交联和热物理性质.
主要成果:
- PPE-BMI树脂表现出显著增强的介电特性 (低Dk和Df) 和尺寸稳定性.
- 即使经过严格的湿度-热度可靠性测试,性能也保持不变.
- 增加BMI含量导致热膨胀系数显著降低.
- 分子动力学模拟证实,由于BMI的纳入,自由体积减少,交联密度增加.
结论:
- 开发的PPE-BMI树脂由于其优越的介电性能和热稳定性,在6G时代对先进的PCB应用非常有希望.
- 加入BMI交叉连接器有效地提高了材料的性能,通过限制链的移动性和增加交叉连接.
- 该材料的潜力进一步证明了其成功透到玻璃和液晶织物中,用于实际的PCB制造.
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