沉重金属的表征和固化在炼的固体废物陶中,这些陶是由提取炉渣制成的
Haiping Xiao1, Zhengwang Guo2, Yingao Huo1
1School of Energy, Power and Mechanical Engineering, North China Electric Power University, Beinong Road 2#, Huilongguan Town, Changping District, Beijing, 102206, China.
Environmental science and pollution research international
|December 2, 2024
概括
这项研究将危险的提取炉渣转化为耐用陶,使用飞灰和脱硫石膏. 由此产生的固体废物陶有效固化重金属,为工业废物利用提供了可持续的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 废物管理 废物管理
背景情况:
- 提取炉渣是一种含有重金属的危险废物.
- 这种废渣的经济和安全利用带来了重大挑战.
- 开发用于无害地重新利用工业固体废物的方法至关重要.
研究的目的:
- 为了将提取炉渣转化为固体废物陶.
- 为了研究这些陶的重金属固化能力.
- 评估在这个过程中使用飞灰和脱硫石膏的可行性.
主要方法:
- 用于相位分析的X射线衍射 (XRD).
- 炼实验以确定重金属的固化.
- 扫描电子显微镜 (SEM) 用于微观结构检查.
- 废渣,飞灰和石膏的不同组成,经过受控烧结.
主要成果:
- 在最佳条件下 (60%的渣,20%的石膏,20%的飞灰,1180°C) 产生的陶具有43.02MPa的曲强度和0.74%的吸水率.
- 对Cr,Mn,Ni,Cu和Zn的固化比率超过97%.
- 确定的主要阶段是二氧化和血,二氧化有效固化了Zn,Mn和Ni,而螺旋固化了Cr和Cu.
结论:
- 开发的陶系统有效地固化了重金属,将危险的废渣转化为有价值的材料.
- 在烧结过程中形成液相,促进重金属固定和材料密集.
- 这种方法为金固体废物的资源利用提供了一个有前途的途径.
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