根据德拜-斯托克斯-爱因斯坦关系揭示了大型和非同位素玻璃形成分子的双重性质
Abin Raj1, Marzena Rams-Baron1, Kajetan Koperwas1
1August Chełkowski Institute of Physics, University of Silesia, 75 Pulku Piechoty 1, 41-500 Chorzow, Poland.
The journal of physical chemistry. B
|December 3, 2024
概括
在形成玻璃的液体中, anisotropy 影响了德拜-斯托克斯-爱因斯坦关系. 分子方向影响旋转放松时间和粘度脱,影响超冷状态下的DSE有效性.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
背景情况:
- 德拜-斯托克斯-爱因斯坦 (DSE) 关系连接了旋转放松时间和剪切粘度,这对于理解形成玻璃的液体至关重要.
- 现有研究强调了这种关系的重要性,但分子异性异性作用仍未得到充分研究.
研究的目的:
- 为了研究分子异构性对玻璃形成液体中德拜-斯托克斯-爱因斯坦关系的影响.
- 为了确定分子方向 (平行或垂直于二极子时刻) 如何影响旋转放松和粘度的脱.
主要方法:
- 介电光谱测量重新定位放松时间.
- 剪切粘度测量. 剪切粘度测量. 剪切粘度测量. 剪切粘度测量.
- 分子动力学 (MD) 模拟来分析重定向机制.
主要成果:
- DSE关系的分解取决于有助于介电反应的异构旋转元件.
- 对于与长轴垂直的二极体的分子,DSE关系在超冷状态中保持.
- 对于具有短轴介电贡献的分子,在中间超冷状态中发生了与 DSE 预测的偏离.
结论:
- 对玻璃形成液体而言, anisotropy 是德拜-斯托克斯-爱因斯坦关系的一个关键因素.
- 特定的异性质运动,而不是重定向机制本身,决定了异性质系统中的DSE行为.
- 了解异构运动是解释超冷液体中DSE关系偏差的关键.
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