提高电池P'2 Na2/3MnO2电极性能的有效途径
Yosuke Ugata1,2, Tomohiro Kuriyama1, Naoaki Yabuuchi1,2
1Department of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan. yabuuchi-naoaki-pw@ynu.ac.jp.
概括
这项研究重新审视了P.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (SIB) 是离子电池的一个有希望的替代品.
- 层层的过渡金属氧化物是SIB的关键阴极材料.
- P'2型Na2/3MnO2具有潜力,但在可循环和Mn溶解方面面临挑战.
研究的目的:
- 为了研究和提高P'2型Na2 / 3MnO2作为SIB阴极的电化学性能.
- 确定影响该材料循环利用性和稳定性的关键因素.
- 探索抑制溶解和改善长期循环的策略.
主要方法:
- P'2型Na2/3MnO2的电化学循环在不同的较低切断电压下.
- 使用高度缩的电解质来最大限度地减少自由溶剂分子.
- 在延长的循环周期 (300个循环) 中分析容量保留和循环能力.
主要成果:
- 增加下切断电压显著提高Na2 / 3MnO2的循环性,尽管可逆容量有所减少.
- 高度的电解质有效地抑制了从阴极材料中溶解的离子.
- 在优化条件下,在300个周期内实现了超过85%容量保留的稳定循环.
结论:
- 在离子电池应用中,P'2型Na2/3MnO2可以有效地稳定.
- 使用高度溶液的电解质工程对于减轻材料降解至关重要.
- 优化循环电压和电解质组成可以提高基于Mn的阴极的实际可行性.
相关概念视频
Batteries and Fuel Cells
27.0K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.0K
Voltaic/Galvanic Cells
56.8K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
56.8K


