分析矿山水对煤炭自燃的复合效应及其在煤炭火灾预防中的应用
Bo Tan1, Liyang Gao1, Xiaomeng Li1
1School of Emergency Management and Safety Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China.
The Science of the total environment
|December 5, 2024
概括
矿井水处理增加了煤炭自燃的风险. 酸度增强了这种效果,主要是由于水的酸度.
科学领域:
- 矿井的火力控制系统.
- 煤炭自燃 (CSC) 是一种自燃的方法.
- 环境地质化学环境地质化学
背景情况:
- 与原煤相比,矿山水处理往往会增加煤炭自燃 (CSC) 的风险.
- 现有的关于矿山水对CSC影响的研究是有限的,并不完全代表真正的矿山环境或矿山水组件的综合影响.
研究的目的:
- 研究实际矿水特性对煤炭自燃 (CSC) 过程的复合效应.
- 分析不同类型和条件的矿井水如何影响CSC参数.
主要方法:
- 在不同条件下,在不同类型的矿山水中浸泡煤炭样本的制备.
- 热重力测量分析 (TGA) 用于确定特征温度和激活能量.
- 红外 (IR) 光谱法用于分析有机功能组.
- 气体分析以量化CO和CO2释放量.
主要成果:
- 矿井水处理显著增加了煤炭的初始特征温度 (T1),高达11°C.
- 随后的特征温度 (T2-T4) 降低了高达13°C.
- 显而易见的激活能量减少了32% (40.6 KJ/mol).
- 与原煤相比,CO和CO2释放量增加了1-2倍,有机功能组增加了1.1至1.8倍.
- 这些促进作用随着矿山水酸度的增加而加剧.
结论:
- 矿井水通常促进煤炭自燃 (CSC) 活动.
- 水的膨胀作用是主要的促进因素,而无机盐具有抑制作用,但不是在足够的度下.
- 这些发现为CSC控制和矿山水在采矿操作中的利用提供了理论支持.
相关概念视频
Constant Volume Calorimetry
26.9K
Calorimeters are useful to determine the heat released or absorbed by a chemical reaction. Coffee cup calorimeters are designed to operate at constant (atmospheric) pressure and are convenient to measure heat flow (or enthalpy change) accompanying processes that occur in solution at constant pressure. A different type of calorimeter that operates at constant volume, colloquially known as a bomb calorimeter, is used to measure the energy produced by reactions that yield large amounts of heat and...
26.9K
Sample Preparation for Analysis: Advanced Techniques
300
Accurate analysis of complex samples often requires advanced preparation techniques to achieve reliable and reproducible results. Samples containing inorganic or organic materials can be challenging to dissolve or decompose effectively. Standard sample preparation methods include acid digestion, fusion, dry ashing, and wet digestion.
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
300
Pozzolans
101
Pozzolans are siliceous or aluminous materials blended with Portland cement. They interact with the calcium hydroxide produced during the hydration of Portland cement and contribute to improved strength and durability of concrete. The pozzolanic activity, a measure of a pozzolan's effectiveness, is typically assessed using the strength activity index, as defined in ASTM C 618-93, which calculates the ratio of the compressive strength of cement mixtures with and without pozzolan.
Fly ash is...
Fly ash is...
101
Acid Attack on Concrete
184
When acids come into contact with concrete, they initiate a chemical reaction that dissolves the hydrated cement paste. This process leads to softening and structural weakening of the concrete. This issue is commonly observed in environments such as chimneys, sewers, and industrial settings. The severity of the damage increases as the pH of the water interacting with the concrete drops below 6.5. In particular, a pH under 4.5 can cause significant concrete damage.
The rate at which hydrogen...
The rate at which hydrogen...
184
Waterproofing and Anti-Bacterial Admixtures in Concrete
74
Concrete's susceptibility to water absorption is due to the capillary action within the pores of its hydrated cement paste. This action draws water in, creating the need for waterproofing admixtures to prevent such penetration. The efficacy of these admixtures is contingent upon the water pressure, with variations arising from different conditions such as rain, capillary rise, or hydrostatic pressure in structures intended to hold water.
Waterproofing admixtures render concrete hydrophobic,...
Waterproofing admixtures render concrete hydrophobic,...
74


