使用优化的单色能量分散式X射线光来确定可可和土壤样本中的度
Jesse Dekeyrel1, Rachel Atkinson2, Eduardo Chavez3
1Division of Soil and Water Management, KU Leuven, Heverlee, Belgium.
Heliyon
|December 6, 2024
概括
一种新的单色能量分散式X射线光 (MEDXRF) 方法提供了一种更快,更便宜的方法来监测可可中的 (Cd). 这种技术提供了与传统ICP-MS可比的准确结果,有助于遵守食品安全法规.
科学领域:
- 农业科学 农业科学
- 分析化学 分析化学
- 食品安全 食品安全
背景情况:
- 由于食品安全限制,可可中的 (Cd) 监测需求日益增加.
- 传统的ICP-MS方法耗时且昂贵.
- 射线光 (XRF) 具有潜力,但其检测极限很高.
研究的目的:
- 检查一种优化的单色能量分散式X射线光 (MEDXRF) 方法用于可可中的Cd分析.
- 建立MEDXRF作为常规Cd监控ICP-MS的可行,成本有效的替代方案.
主要方法:
- 优化MEDXRF用于可可豆,液体,叶子和土壤中的Cd检测.
- 每个样品的测量时间为200秒.
- 为了准确性和相关性,MEDXRF结果与ICP-MS进行比较.
主要成果:
- 生物样本达到0.178毫克/千克,土壤达到0.205毫克/千克的平均量化限度 (LOQ).
- 在各种样本类型中,在MEDXRF和ICP-MS结果之间发现了强烈的相关性 (R2 = 0.984).
- 低变化系数 (<15%) 表明Cd度高于LOQ.的可再生性良好.
结论:
- 优化的MEDXRF方法是可可供应链中常规Cd监测的经济有效和高效的替代方案.
- 该技术的准确性和速度支持大规模查和科学研究.
- 可以将MEDXRF扩展到监测各种作物中其他重金属的监管合规性.
相关概念视频
Atomic Absorption Spectroscopy: Lab
311
For AAS measurements, samples must be introduced as clear solutions, often requiring extensive preliminary treatment to dissolve materials like soils, animal tissues, and minerals. Common methods for sample preparation include treatment with hot mineral acids, wet ashing, combustion in closed containers, high-temperature ashing, or fusion with reagents.
Solutions containing organic solvents, such as low-molecular-mass alcohols, esters, or ketones, enhance absorbances by increasing...
Solutions containing organic solvents, such as low-molecular-mass alcohols, esters, or ketones, enhance absorbances by increasing...
311
Atomic Emission Spectroscopy: Overview
1.5K
Atomic emission spectroscopy (AES) is an analytical technique used to determine the elemental composition of a sample by analyzing the light emitted from excited atoms. In AES, atoms in a sample are excited to higher energy levels by thermal energy from high-temperature sources, such as plasma, arcs, or sparks. When these excited atoms return to lower energy states, they emit light at specific wavelengths characteristic of each element. The resulting atomic emission spectrum, which consists of...
1.5K
X-ray Diffraction of Biological Samples
3.8K
X-ray diffraction or XRD is an analytical tool that utilizes X-rays to study ordered structures such as crystalline organic and inorganic samples, polycrystalline materials, proteins, carbohydrates, and drugs.
According to Bragg's law, when X-rays strike the sample positioned on a stage, the rays are scattered by the electron clouds around the sample atoms. The X-ray diffraction or scattering is caused by constructive interference of the X-ray waves that reflect off the internal...
According to Bragg's law, when X-rays strike the sample positioned on a stage, the rays are scattered by the electron clouds around the sample atoms. The X-ray diffraction or scattering is caused by constructive interference of the X-ray waves that reflect off the internal...
3.8K


