几乎内在的Pb-Sn Perowskites的无添加剂的连续热蒸发
Lara M van der Poll1, Niels van Silfhout1, Jasmeen Nespoli1
1Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, Delft, 2629 HZ, The Netherlands.
Small methods
|December 6, 2024
概括
连续的热蒸发产生高质量的formamidinium锡化物 (FAPb0.5Sn0.5I3) 薄膜,用于高效的矿太阳能电池. 这种可扩展的方法为低频段间隙应用提供了增强的材料特性.
科学领域:
- 材料科学 材料科学 材料科学
- 太阳能光伏发电是如何实现的
- 固态化学 固态化学
背景情况:
- 串联矿太阳能电池需要低带间隙 (LBG) 材料来超越单环节效率限制.
- 在矿结构中,用锡 (Sn2+) 部分替代 (Pb2+),使LBG材料成为可能.
研究的目的:
- 开发一种可扩展的方法,用于生产高质量的FAPb0.5Sn0.5I3膜,用于LBG矿应用.
- 描述Sn-Pb合金矿膜的结构和光电子特性.
主要方法:
- 在真空中对PbSnI4和formamidinium iodide (FAI) 的连续热蒸发 (sTE).
- 在200°C时回火,形成颗粒大小 (>1μm) 的晶状薄膜.
- 光导度测量以评估载体寿命和移动性;结构分析用于间传播研究.
主要成果:
- sTE产生高度定向的,结晶的FAPb0.5Sn0.5I3膜,平均颗粒大小大于1μm.
- 实现了超过2μs的载体寿命和100cm左右的移动性.
- 与没有添加剂的螺旋涂层样本相比,sTE薄膜显示出更高的光导率.
结论:
- 连续热蒸发是一种有前途的可扩展技术,用于制造高质量的LBG矿膜.
- 该方法产生了优秀的光电子特性,适用于先进的矿太阳能电池设计.
- 了解互传播对于优化电影转换和性能至关重要.
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