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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Diffusion is the passive movement of substances down their concentration gradients—requiring no expenditure of cellular energy. Substances, such as molecules or ions, diffuse from an area of high concentration to an area of low concentration in the cytosol or across membranes. Eventually, the concentration will even out, with the substance moving randomly but causing no net change in concentration. Such a state is called dynamic equilibrium, which is essential for maintaining overall...
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Carrier Transport01:21

Carrier Transport

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The generation of electrical current in semiconductors is fundamentally driven by two mechanisms: drift and diffusion. These processes are essential for the functionality and performance of semiconductor-based devices.
Drift Current:
The drift of charge carriers is started by an external electric field (E). Charged particles, such as electrons and holes, experience an acceleration between collisions with lattice atoms. For electrons, this results in a drift velocity (vd) given by:
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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.2K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Updated: Jun 5, 2025

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy
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实用全固态电池的化学竞争扩散

Zhongsheng Dai1, Xuan Sun1, Renjie Chen1,2,3

  • 1Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China.

Journal of the American Chemical Society
|December 7, 2024
PubMed
概括
此摘要是机器生成的。

一种新的异原子策略通过定氧气和调节离子扩散来稳定固态电池中的富含的阴极. 这提高了高压电源应用的周期寿命和安全性.

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科学领域:

  • 材料科学
  • 电化学
  • 固态电池

背景情况:

  • 丰富的阴极的热安全问题需要先进的电池设计.
  • 挑战包括现有系统中的级联反应和化学-机械降解.
  • 完全固态电池为提高安全性提供了有希望的替代方案.

研究的目的:

  • 用于稳定丰富的阴极及其与固体电解质的接口.
  • 阐明异原子辅助稳定机制.
  • 提高硫化物固态电池的循环寿命和性能.

主要方法:

  • 不同原子的化学竞争扩散策略.
  • 理论计算和多尺度的实地/现场表征.
  • 原子级化学竞争扩散和拓的分析.

主要成果:

  • 在大量中,异构原子充当"氧",防止氧的演变.
  • 表面丰富的异质原子与形成一个离子"扩散调节器".
  • 压电层提高了接口兼容性,并削弱了空间电荷层.
  • 设计的电池在4.5V的120个循环后保持了97.3%的容量.

结论:

  • 不同原子策略有效地稳定了富含Ni的阴极和固体电解质接口.
  • 了解原子级扩散和接口调节是电池性能的关键.
  • 这项研究揭示了固态电池中的压电材料的结构功能关系.