在区域范围内对来自土壤的POPs输出流的综合建模:全面的方法
Xinyue Chen1, Meie Wang2, Tian Xie2
1State Key Laboratory of Urban and Regional Ecology, Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China.
Environment international
|December 7, 2024
概括
一个新的模型整合了自然减弱和水文过程,以估计来自土壤的区域性持久有机污染物 (POP) 输出流量. 水洗是主要的途径,土壤有机碳含量是关键因素.
科学领域:
- 环境科学 环境科学
- 环境化学环境化学
- 水文学的水文学
背景情况:
- 图形尺度模型无法充分捕捉区域污染物运输.
- 现有的研究缺乏区域范围内的持久有机污染物 (POP) 输出流量的综合模型.
研究的目的:
- 开发和验证一个综合自然减弱和水文过程的综合模型,以估计区域范围内的土壤POPs输出流量.
主要方法:
- 结合自然减弱 (降解,挥发,植物吸收) 与水文运输 (浸,水洗,沉积物运输).
- 使用来自中国石化地区的数据验证了该模型.
- 将模型性能与质量平衡和神经网络模型进行比较.
主要成果:
- 水洗是 (Phe) (94.67%) 和 (BaP) (98.33%) 的主要输出途径.
- 由于更高的挥发性和溶解性,Phe显示出比BaP更广泛的输出流量范围.
- 与之前的模型相比,开发的模型表现出优异的性能 (R2>0.7,RMSE<3%).
- 土壤有机碳质量分数 (foc) 被确定为最有影响力的参数.
结论:
- 该研究提供了一个强大的,综合模型,用于准确的区域POPs输出流量估计.
- 强调了水冲洗和土壤特性在POPs运输中的关键作用.
- 解决了区域污染物命运建模环境研究的重大缺口.
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