自愈,阻燃和抗紫外线的素衍生的环氧木材涂层与希夫基结构的基础结构
Yuqing Liang1, Hanwen Zuo1, Mingyu Wen1
1Wood Material Science and Engineering Key Laboratory, College of Materials Science and Engineering, Beihua University, Jilin, Jilin 132013, PR China.
International journal of biological macromolecules
|December 8, 2024
概括
这项研究引入了一种来自生物质的新型,自我愈合,阻燃环氧涂层. 新的涂层为木材提供了更好的保护,解决了可持续性和消防安全方面的问题.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 可持续化学 可持续化学
背景情况:
- 传统的环氧树脂易燃,不可回收,且依赖石油,阻碍了防火和可持续发展.
- 需要先进的涂层,为木材等材料提供更好的安全性和环境配置文件.
研究的目的:
- 开发一种基于生物质的,自我修复的,具有增强木材保护性能的阻燃环氧涂层.
- 为传统的以石油为基础的环氧树脂创造一个可持续的替代品.
主要方法:
- 在瓦尼林和OA-POSS之间使用希夫基反应合成了一种瓦尼林中间体 (VAP).
- 通过将DOPO纳入VAP,开发了一种基于生物质的阻燃剂 (VAPD).
- 使用VAPD作为环氧树脂的固化剂,以创建VAPD/EP涂层.
主要成果:
- VAPD-5/EP涂层在35分钟内显示出100%的自我愈合,并且具有出色的紫外线屏蔽.
- 在UL-94测试中获得V-0评级,氧气限制指数 (LOI) 为29.3%.
- 降低了38%的峰值热释放率 (pHRR),并显示了6H硬度和4B粘合.
结论:
- 制定了一种简单的策略,用于制备具有综合性质的自我愈合,阻燃环氧涂层.
- 开发的涂层为木材材料保护提供了可持续和高性能的解决方案.
- P-N-Si阻燃系统在消防安全和材料耐用性方面提供了显著的改进.
相关概念视频
Wood Products
79
Wood products encompass a broad range of materials crafted from wood strands, veneers, lumber, and even waste wood-like shreds, designed for both structural and nonstructural purposes. Various specialized wood products have been developed to enhance strength, durability, and versatility in building applications.
Glue-laminated wood, often referred to as glulam, combines multiple smaller pieces of dimensional lumber using adhesives to form a single, larger piece. Cross-laminated timber consists...
Glue-laminated wood, often referred to as glulam, combines multiple smaller pieces of dimensional lumber using adhesives to form a single, larger piece. Cross-laminated timber consists...
79
Wood Panel Products
70
Wood panel products are essential materials used in construction for applications such as flooring, siding, and roofing, typically available in standard dimensions of 4 feet by 8 feet, with thicknesses varying from one-quarter of an inch to one and one-eighth inches. Among the most common types of wood panels is plywood, which is produced by gluing multiple layers of thin wood veneers under pressure. The grain of the outer veneers runs lengthwise, while the grains of the interior layers run...
70
Seasoning of Wood
86
Seasoning of wood is a crucial process aimed at reducing and stabilizing the moisture content within the wood to prevent future shrinkage, structural damage, or aesthetic issues once the wood is used in construction. Wood naturally swells when it absorbs moisture and contracts as it dries.
Achieving equilibrium moisture content is the goal of seasoning; this is the point where the wood's moisture content stabilizes to align with the moisture levels of the surrounding environment. Proper...
Achieving equilibrium moisture content is the goal of seasoning; this is the point where the wood's moisture content stabilizes to align with the moisture levels of the surrounding environment. Proper...
86
Lumber
108
Lumber is derived from logs which are harvested, debarked, and processed into long pieces with a rectangular cross-section. The transformation of logs into lumber involves multiple steps, beginning with an automated saw that slices the log into slabs. These slabs are then transported via a conveyor belt to smaller saws, where they are cut into square-edged pieces of specific widths.
Initially, the surfaces of these lumber pieces are rough, and their dimensions may vary slightly from one end to...
Initially, the surfaces of these lumber pieces are rough, and their dimensions may vary slightly from one end to...
108
Wood Surfacing
88
Wood surfacing is a critical finishing process designed to smoothen the wood surface, enhance its dimensional accuracy, and make handling safer. This process compensates for potential shrinkage during the seasoning phase by marginally increasing the wood dimensions before surfacing. It also helps correct some distortions that may occur as the wood dries.
The equipment used in the surfacing process is a plane equipped with rotating blades. This tool efficiently smoothens the wood surface and can...
The equipment used in the surfacing process is a plane equipped with rotating blades. This tool efficiently smoothens the wood surface and can...
88
Lumber Defects
103
Lumber defects, which can affect both the appearance and structural integrity of wood, include a variety of growth and manufacturing flaws. Growth defects such as knots and knotholes occur where branches were once attached to the tree trunk, with knotholes forming when these knots fall out. Other natural defects include decay and insect damage, which compromise the wood's strength and durability.
Shakes are minor fractures that run along or across the wood's annual rings, while wane is...
Shakes are minor fractures that run along or across the wood's annual rings, while wane is...
103


