表面和在性氧化在Ni基电催化剂中的作用
Xiaoyu Tian1, Jiaxiang Liu2, Pengcheng Zhao1
1State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai Institute of Pollution Control and Ecological Security, Shanghai, 200092, P.R. China.
基于的催化剂在离子交换膜燃料电池中的性氧化反应中表现有前途. 用过渡金属合金通过优化电子特性和减轻氧化物中毒来提高活性和稳定性.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
背景情况:
- 阳离子交换膜燃料电池 (AEMFC) 需要高效的非贵金属催化剂来进行氧化反应 (HOR).
- (Ni) 是性HOR的有前途的候选物,但其活性较低,稳定性不佳.
- 了解吸附基物种 (OHad) 的作用对于提高Ni基催化剂性能至关重要.
研究的目的:
- 系统地探索电子沉积Ni基催化剂 (Ni5Mo,Ni25Co,Ni14W,Ni) 上的性HOR.
- 研究过渡金属合金对Ni催化剂活性和稳定性的影响.
- 阐明OHad诱导失活化的机制及其依赖OHad结合能 (OHBE) 的机制.
主要方法:
- 基于Ni的模型催化剂的电化学沉积.
- 分析催化剂性能的光谱研究.
- 密度函数理论 (DFT) 计算,以了解电子结构和结合能.
主要成果:
- 在Ni催化剂中的过渡金属合金 (Mo,Co,W) 通过电荷转移和Ni3d带中心下移来增强HOR活性.
- 在HOR特异性活动和结能 (HBE) 之间观察到火山类型的关系.
- 强烈吸附的OHad物种使Ni活性位点失活,其失活潜力取决于OHBE.
结论:
- 将Ni与过渡金属合金是一种有效的策略,用于设计强大高效的性HOR催化剂.
- 了解和减轻OHad中毒是提高催化剂稳定性的关键.
- 这项研究为HOR机制提供了关键的见解,并为AEMFCs提供了合理催化剂设计的途径.
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