碳量子点 (CQD) 的环保合成来自花皮,用于敏感的阿弗拉托克辛B1 (AFB1) 检测
Hatice Yuncu1, Hayrunnisa Nadaroglu1,2, Ebru Bozkurt1,3
1Department of Nano‑Science and Nano‑Engineering, Institute of Science, Ataturk University, Erzurum 25240, Turkey.
Toxicology reports
|December 9, 2024
概括
从子皮废物中合成的绿色光碳量子点 (CQD) 提供了一种稳定,环保的方法来检测阿弗拉托克辛B1 (AFB1). 这种新的方法在各种食品样本中提供了灵敏而准确的AFB1检测.
科学领域:
- 材料科学 材料科学 材料科学
- 分析化学 分析化学
- 环境科学 环境科学
背景情况:
- 碳量子点 (CQD) 是具有独特光学和电子特性的纳米材料.
- 农业废物,如子皮 (HH),代表了可持续材料合成的未充分利用的资源.
- 甲素B1 (AFB1) 是一种有毒的真菌代谢物,对食品安全构成重大风险.
研究的目的:
- 通过热解法从子的废物中合成绿色光CQD.
- 为了描述合成的HH-CQD的光学和结构性质.
- 评估HH-CQDs在食品样本中敏感和选择性检测AFB1的潜力.
主要方法:
- 花皮的热解以合成CQDs.
- 使用UV-Vis,光谱学,TEM,FT-IR,XRD和XPS进行表征.
- 使用光共振能量转移 (FRET) 检测AFB1,并评估pH依赖的光发光.
主要成果:
- 合成了具有良好的稳定性,水溶性和生物相容性的球形HH-CQD (2-10nm).
- 观测到的光量子收益率为0.04和光发射峰值在451nm.
- 选择性和敏感的AFB1检测在线性范围 (25-250 ppm,R2 = 0.9936) 和高精度的真实食品样本中实现.
结论:
- 从农业废物中可以合成环保且具有成本效益的HH-CQD.
- 在食品矩阵中检测AFB1的光探针中,HH-CQD显示出有前途的潜力.
- 开发的方法为食品安全分析提供了一个可持续的替代方案.
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