高压低温研究LnCa4O(BO3) 3 (Ln = Pr, Nd, Gd, Er, Tm) 的研究结果
Fatiha Azrour1, Romain Viennois1, Jérôme Long1,2
1ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier 34293, France.
ACS omega
|December 9, 2024
概括
这项研究揭示了兰化氧酸盐中独特的位点乱和热膨胀. 观察到不同的行为,表明NdCa4O(BO3) 3.3.的潜在不同的基本状态.
科学领域:
- 固态化学 固态化学
- 材料科学是一种材料科学.
- 晶体学 晶体学是指结晶学.
背景情况:
- 兰他尼德氧化酸盐 (LnCa4O(BO3) 3) 是一个经过充分研究的材料类.
- 了解它们的结构性质对于潜在的应用至关重要.
研究的目的:
- 为了研究LnCa4O(BO3) 3 (Ln = Pr, Nd, Gd, Er, Tm) 中的位点乱和热膨胀.
- 在高压和低温下确定NdCa4O(BO3) 3和ErCa4O(BO3) 3的可压缩性.
- 为了重新评估这些氧化酸盐的基本状态.
主要方法:
- 从100到300K的单晶结构研究.
- 在低温下高压同步X射线衍射.
- 基于离子半径的热膨胀和压缩性的分析.
主要成果:
- 观察到明显的热膨胀行为,与兰坦化离子半径相关.
- NdCa4O ((BO3) 3) 和ErCa4O ((BO3) 3) 在压力下表现出不同的压缩性.
- 卫星反射和50K的NdCa4O(BO3) 3中的三重a参数表明了一个新的地面状态.
结论:
- LnCa4O(BO3) 3 的位点乱和热膨胀受到类离子大小的强烈影响.
- 这些材料的压缩性随着组成和结构顺序而有很大变化.
- 目前的证据表明,人们对这种兰化氧酸盐家族的基本状况有了改进的理解.
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