基于共价三的有机聚合物修改了电离源,用于快速和灵敏地分析植物雌激素
1Chinese Academy of Inspection and Quarantine, Beijing, 100176, China; School of Traditional Chinese Materia Medica, Shenyang Pharmaceutical University, Shenyang, 110016, China.
Food chemistry
|December 9, 2024
概括
一种新方法使用基于共价三的有机聚合物在钢 (TCOPs-S) 上,以快速,灵敏地检测食品中的植物雌激素. 这种方法通过克服低度和复杂样本矩阵的挑战来增强食品安全分析.
科学领域:
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
- 食品科学 食品科学 食品科学
背景情况:
- 植物雌激素监测对于食品安全至关重要.
- 低度和复杂的食物矩阵带来了分析挑战.
- 现有的方法需要提高灵敏度和效率.
研究的目的:
- 开发一种用于检测植物雌激素的新型吸附材料.
- 建立一种快速而敏感的植物雌激素分析方法.
- 解决植物雌激素食品安全分析方面的挑战.
主要方法:
- 在钢基板 (TCOPs-S) 上以共价三酸为基础的有机聚合物的现场合成.
- 使用TCOPs-S作为固相微提取的吸附剂.
- 在环境质谱学 (钢基板喷雾质谱学 - SS-MS) 中使用TCOPs-S作为电离源的应用.
主要成果:
- 开发的SS-MS方法实现了对植物雌激素检测的高灵敏度,LODs从0.50到0.75μg/kg.
- 证明了令人满意的康复 (84.08-109.15%).
- 在TCOP中,含量和多孔性增加,通过结增强含有基的植物雌激素的吸附.
结论:
- 新的TCOPs-S材料和SS-MS方法为植物雌激素检测提供了灵敏和快速的方法.
- 该方法的水友性质和吸附性质有利于分析水溶液中的植物雌激素.
- 这种技术显示出用于常规食品安全分析的巨大潜力.
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