捐赠体-受体环烯的光氧激活:在 [3+2] 循环添加反应中的迪斯顿基离子活性

Subhashis Mondal1, Saradindu Debnath1, Rabindranath Lo2

  • 1Department of Chemistry and Chemical Biology, Indian Institute of Technology (ISM) Dhanbad, Jharkhand, 826004, India.

概括

光电氧催化使不可极化的基与捐赠体接受体环烯的循环添加成为可能,克服了易斯酸催化方法的局限性. 这种新的方法通过 [3σ+2σ] 循环添加产生了高度替代的环丹和环丹,以及双环[3.1.1] 丹.

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