停止氧的进化,以实现层阴极的长周期寿命
Haoji Wang1, Jinqiang Gao1, Yu Mei1
1College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China.
Angewandte Chemie (International ed. in English)
|December 11, 2024
概括
研究人员通过使用增强来增强电子结构障碍 (ESD) 来增强高压电池阴极. 这一策略抑制了氧气的损失和降解,改善了循环稳定性,并使更安全,高能量密度的电池成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 电池技术 电池技术
背景情况:
- 高压阴极对于高能量密度电池至关重要.
- 氧氧还氧化化学提供高能量密度,但遭受氧气损失和降解.
研究的目的:
- 开发一种提高氧氧还氧阴极稳定的策略.
- 在高脱状态下改善电子结构障碍 (ESD),以提高性能.
主要方法:
- 密度函数理论 (DFT) 计算以阐明机制.
- 软/硬X射线吸收光谱分析结构演变.
- 具有不同的层阴极的比较分析.
主要成果:
- 增强有效地增强了电子结构障碍 (ESD).
- 观察到抑制的P-O结构演变和稳定的TMO6八面体环境.
- 层阴极中的高状态抑制了有害的O'3相形成.
- 在100个循环的1C下达到90.1%的容量保留,在4.4V的300个循环的2C下达到76.1%,在4.4V的2C下达到76.1%.
结论:
- 通过工程控制ESD是稳定的氧氧氧化还原的关键.
- 这种方法显著提高了高压循环稳定性.
- 为先进的高能耗,长周期和安全电池铺平了道路.
相关概念视频
Electrolysis
26.0K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.0K
Batteries and Fuel Cells
27.0K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.0K
Voltaic/Galvanic Cells
56.8K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
56.8K


