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Updated: Jun 5, 2025

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
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作为聚氧甲酸盐基金属有机框架中的质子来源的非协调性基团增强了质子导电

Xin Zheng1, Yu-Ming Cui1, Ning-Hao Wang1

  • 1Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry, Jilin Provincial International Joint Research Center of Photo-functional Materials and Chemistry, School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China.

Inorganic chemistry
|December 11, 2024
PubMed
概括

新的基于聚氧甲的金属有机框架 (POMOFs) 显示了增强的质子导电性. 由于其连接体设计,CUST-961表现出卓越的性能,为先进的质子导电材料提供了洞察力.

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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
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When a carbonyl compound is treated with a strong base, the α position gets deprotonated to give a resonance-stabilized intermediate called an enolate. Enolates are ambident nucleophiles because they possess two nucleophilic sites that can attack an electrophile owing to the delocalization of the negative charge between the α carbon and oxygen atoms. When the oxygen atom attacks an electrophile, it is called O-attack, whereas electrophilic attack via the α carbon is known as...
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