通过与液态水接触而形成的水性离子介导的酸催化
Yue Liu1,2, Chen Luo1, Shuai Wang3
1Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
Journal of the American Chemical Society
|December 12, 2024
概括
石作为弱固体酸,释放离子 (H3O+) 进入水中. 这项研究表明这些外部离子, 而不是内部离子, 驱动催化, 就像纤维素水解一样,
科学领域:
- 材料科学
- 催化剂
- 物理化学
背景情况:
- 焦化物是用于可持续化学生产的催化剂的固体酸.
- 它们的催化活性通常归因于它们多孔结构中的内在酸位.
研究的目的:
- 为了阐明在水性介质中石的酸性质.
- 确定热石在水中催化反应的机制.
- 澄清外结晶与内结晶酸位的作用.
主要方法:
- 通过静电排斥形式主义在水中研究过石解离.
- 量化的超晶离子 (H3O+) 度.
- 通过纤维素水解探测了催化活性.
主要成果:
- 石作为弱聚酸,分离形成额外晶体离子 (H3O+).
- 离合范围受到热岩框架内的静电排斥的限制.
- 通过纤维素水解证明的催化,完全通过这些超晶体H3O+离子发生.
- 反应速率与H3O+度成正比,不依赖于化物结构或含量.
结论:
- 在水中以酸催化反应仅通过超晶体离子 (H3O+) 进行.
- 这一发现弥合了对固体和液体酸催化物的理解.
- 解决了无法进入晶体内酸位的基板机制.
更多相关视频
相关概念视频
Catalysis
26.6K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
26.6K
Acid-Catalyzed Hydration of Alkenes
13.7K
Alkenes react with water in the presence of an acid to form an alcohol. In the absence of acid, hydration of alkenes does not occur at a significant rate, and the acid is not consumed in the reaction. Therefore, alkene hydration is an acid-catalyzed reaction.
13.7K
Alkynes to Aldehydes and Ketones: Acid-Catalyzed Hydration
8.2K
Introduction
Analogous to alkenes, alkynes also undergo acid-catalyzed hydration. While the addition of water to an alkene gives an alcohol, hydration of alkynes produces different products such as aldehydes and ketones.
Analogous to alkenes, alkynes also undergo acid-catalyzed hydration. While the addition of water to an alkene gives an alcohol, hydration of alkynes produces different products such as aldehydes and ketones.
8.2K
Aldehydes and Ketones with Water: Hydrate Formation
3.1K
An oxygen-based nucleophile, like water, can undergo addition reactions with aldehydes and ketones. The reaction leads to the formation of hydrates, also referred to as 1,1-diols or geminal diols.
The formation of hydrates is a reversible reaction. Hydrate formation is influenced by steric and electronic factors accompanying the alkyl substituents on the carbonyl group: The rate of hydrate formation increases with a decrease in the number of alkyl groups attached to the carbonyl carbon. Hence,...
The formation of hydrates is a reversible reaction. Hydrate formation is influenced by steric and electronic factors accompanying the alkyl substituents on the carbonyl group: The rate of hydrate formation increases with a decrease in the number of alkyl groups attached to the carbonyl carbon. Hence,...
3.1K
Acid Halides to Carboxylic Acids: Hydrolysis
2.5K
Hydrolysis of acid halides is a nucleophilic acyl substitution reaction in which acid halides react with water to give carboxylic acids. The reaction occurs readily and does not require acid or a base catalyst.
As shown below, the mechanism involves a nucleophilic attack by water at the carbonyl carbon to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen π bond along with the departure of a halide ion. A final proton transfer step yields carboxylic...
As shown below, the mechanism involves a nucleophilic attack by water at the carbonyl carbon to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen π bond along with the departure of a halide ion. A final proton transfer step yields carboxylic...
2.5K
Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration
8.3K
The rate of acid-catalyzed hydration of alkenes depends on the alkene's structure, as the presence of alkyl substituents at the double bond can significantly influence the rate.
8.3K


