一个绿色的综合工艺,用于石回收:二氧化碳封存与SO2回收相结合
1The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, 430081, Hubei, China; The Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, 430081, Hubei, China; Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking, Wuhan University of Science and Technology, Wuhan, 430081, Hubei, China.
Journal of environmental management
|December 15, 2024
概括
本研究介绍了一种用于石材利用的综合工艺,捕获二氧化碳并回收有价值的SO2. 该方法有效地回收氨,为工业废物提供环保的解决方案.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
背景情况:
- 石 (PG) 堆叠带来了重大的环境挑战.
- 二氧化碳排放和低温二氧化硫 (SO2) 制备需要有效的解决方案.
研究的目的:
- 开发一种用于合石膏 (PG) 利用的综合工艺.
- 为了实现高效的SO2回收和全面利用PG的主要元素.
- 为了减轻PG堆叠,减少二氧化碳度.
主要方法:
- 用氨增强的二氧化碳封存与低温SO2制备相结合.
- 使用硫酸副产品逐步回收氨 (NH3) 和SO2,由铁催化.
- 综合过程的技术经济评估.
主要成果:
- 在40分钟内达到91%的最大PG碳化比,产生微型CaCO3.
- 实现了97%的SO2回收和84%的NH3回收效率.
- 来自PG的 (92%) 和硫 (88%) 的有效利用率得到了实现.
结论:
- 综合工艺为PG管理和硫酸制造提供了一个新的技术参考.
- 每原始PG经过处理,就会捕获0.23二氧化碳,并产生132元的经济效益.
- 在二氧化碳捕获,SO2和NH3回收以及资源利用方面表现出高效率.
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