多元组件协同作用的兴奋剂使高效率的n型PbTe热电器件成为可能
Haoyuan He1, Jia Song1, Ruinian Liang1
1College of Materials Science and Engineering, Guangdong Provincial Key Laboratory of New Energy Materials Service Safety, Guangdong Research Center for Interfacial Engineering of Functional Materials, Institute of Deep Underground Sciences and Green Energy, Shenzhen University, Shenzhen, 518060, P. R. China.
Small (Weinheim an der Bergstrasse, Germany)
|December 16, 2024
概括
高性能n型 Telluride (PbTe) 热电模块是使用Ga,Se和In的合物开发的. 这一策略提高了实用的热电设备的优点 (ZT) 和转换效率.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 能源转换 能源转换
背景情况:
- 高性能n型 Telluride (PbTe) 热电 (TE) 材料对于实际的TE设备至关重要.
- 现有的p型IV-VI型化物具有很高的优点 (ZT),需要在n型对应物中取得进展.
研究的目的:
- 为了优化载体密度,带结构,并降低n型PbTe.Te的网格导热率.
- 提高n型PbTe的热电功率 (ZT) 和转换效率.
主要方法:
- 用 (Ga), (Se) 和 (In) 逐渐化PbTe.
- 使用Fe-Sn混合物作为扩散屏障,用于TE脚的一步烧结.
- n型 PbTe TE 模块的制造和表征.
主要成果:
- 在773 K达到1.6的峰值ZT,在Pb0.979Ga0.02In0.001Te0.96Se0.04中达到1.1的平均ZT (300-773 K).
- 使用Fe-Sn扩散屏障证明了较低的界面接触电阻 (<3μΩcm2) .
- 在n型PbTe单脚TE装置中获得了10.9%的显著转换效率.
结论:
- 多组件协同兴奋剂有效地提高了n型PbTe的性能.
- 使用低温金属的接口连接技术为TE设备的改进提供了新的途径.
- 开发了适合实际应用的高性能n型PbTe TE模块.
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