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酸性酸化物凝对体表面的作用:一个实验室研究
Nadia H Hasan1, Emad Farhan Alkhalidi1, Ammar Abdulghani Qasim2
1Department of Conservative Dentistry, College of Dentistry, University of Mosul, Mosul, Iraq.
Journal of International Society of Preventive & Community Dentistry
|December 16, 2024
概括
酸性酸盐化物 (APF) 凝处理显著增加了树脂改性玻璃离子体水泥到的微剪接强度 (μ-SBS). 这种表面调节增强了水泥对伊特里亚稳定四角陶多晶陶的粘附性.
科学领域:
- 牙科材料科学 牙科材料科学
- 生物材料工程 生物材料工程
- 表面化学 表面化学
背景情况:
- 伊特里亚稳定四角形烯酸多晶 (Y-TZP) 陶由于其机械性能,在牙科中广泛使用.
- 在Y-TZP和化水泥之间实现持久的粘附仍然是一个临床挑战.
- 表面调节方法对于改善牙科水泥对基修复的粘合强度至关重要.
研究的目的:
- 为了评估与两种类型的合金结合的树脂改性玻璃离子体水泥的微剪接强度 (μ-SBS).
- 在酸化化 (APF) 凝调节后,评估合金装配表面的化学和地形变化.
- 为了研究APF凝作为增强合金-水泥粘附的表面处理的有效性.
主要方法:
- 两种材料 (UPCERA HT White 和 BruxZir® 固体) 用1.23%的APF凝进行了制备和调节.
- 扫描电子显微镜 (SEM) 和富里埃变换红外光谱 (FTIR) 用于分析表面变化.
- 进行了微剪粘结强度 (μ-SBS) 测试,以量化和水泥之间的粘结强度.
主要成果:
- FTIR分析揭示了离子交换和酸在APF处理后的表面上形成的酸.
- SEM成像显示了表面变化,包括线条,划痕和解离,在有条件的石的内角表面.
- 在APF凝调节后,在两种石材料中都观察到μ-SBS的显著增加,Upcera的值为1.266 MPa,Bruxzir的值为1.566 MPa.
结论:
- APF凝调节有效地改变了合金表面的化学和地形特征.
- 使用APF凝进行表面处理,可显著提高树脂改性玻璃离子体水泥到的微剪接强度.
- 本研究提出了一种实用且具有成本效益的方法,以提高水泥对Y-TZP陶的粘合力.
相关概念视频
Leveling Effect and Non-Aqueous Acid-Base Solutions
This lesson defines the leveling effect in acidic and basic solutions and its role in aqueous and non-aqueous solutions. It is essential to understand the competing nature of various species in a chemical system.
The Leveling Effect of a Solvent
A generic acid (HA) reacts with the generic base (B-) to yield the corresponding conjugate base (A-) and conjugate acid (HB):
The Leveling Effect of a Solvent
A generic acid (HA) reacts with the generic base (B-) to yield the corresponding conjugate base (A-) and conjugate acid (HB):
Oxidations of Aldehydes and Ketones to Carboxylic Acids
Oxidation of aldehydes and ketones results in the formation of carboxylic acids. Aldehydes, bearing hydrogen next to the carbonyl group, are easily oxidized compared to ketones. This is because an aldehydic proton can easily be abstracted during oxidation.
Aldehydes readily undergo oxidation in strong oxidizing agents such as potassium permanganate and chromic acid. The oxidation can also be carried out using mild oxidizing agents such as silver oxide. In fact, aldehydes can be easily oxidized...
Aldehydes readily undergo oxidation in strong oxidizing agents such as potassium permanganate and chromic acid. The oxidation can also be carried out using mild oxidizing agents such as silver oxide. In fact, aldehydes can be easily oxidized...
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During hydrolysis, the ester is first activated towards nucleophilic attack through the protonation of the carboxyl oxygen atom by the acid catalyst. The protonation makes the ester carbonyl carbon more electrophilic. In the next step, water acts as a nucleophile and adds to the...
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Acids and bases play several important roles in biology. The pH of a biological system can significantly impact the function of biological molecules, including enzymes, proteins, and nucleic acids. For example, enzymes have optimal pH ranges for their activity, and changes in pH can denature or alter their structure, affecting their function. Acids and bases also play a crucial role in cellular signaling and communication. The pH of the extracellular fluid around cells can influence the...
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In acid-base chemistry, the leveling effect refers to the limitation imposed by the solvent on the strength of acids and bases in solution. When a base stronger than the solvent's conjugate base is used, it deprotonates the solvent until the base is entirely consumed, making it ineffective against weaker acids. Conversely, an acid stronger than the solvent's conjugate acid protonates the solvent until the acid is depleted, rendering it ineffective against weaker bases. Essentially, the solvent...

