水的不同模型中的斯托克斯-爱因斯坦关系.
Sergey Khrapak1, Alexey Khrapak1
1Joint Institute for High Temperatures, Russian Academy of Sciences, 125412 Moscow, Russia.
Molecules (Basel, Switzerland)
|December 17, 2024
概括
一个微观的斯托克斯-爱因斯坦关系准确地描述了液态水的特性,与模拟数据和实验发现保持一致. 本研究探讨了它的适用性和局限性,而不需要水力动力半径.
科学领域:
- 物理化学 物理化学
- 计算流体动力学的流体动力学.
- 流动状态理论 流动状态理论
背景情况:
- 斯托克斯-爱因斯坦关系传统上将流体中的扩散和粘度联系在一起.
- 它在微观层面的适用性,特别是对于水,需要进一步研究.
研究的目的:
- 为了评估液态水的微观斯托克斯-爱因斯坦关系的有效性.
- 为了评估其性能而没有纳入水力动力半径.
主要方法:
- 来自五种已建立的水模型的自我扩散和剪切粘度数据的分析.
- 将模拟结果与微观的斯托克斯-爱因斯坦关系进行比较.
主要成果:
- 在水模型数据和微观的斯托克斯-爱因斯坦关系之间发现了很好的一致性.
- 这种关系与液态水的实验数据有着令人印象深刻的一致性.
结论:
- 微观的斯托克斯-爱因斯坦关系非常适用于液态水.
- 提供了关于这种关系的局限性的进一步讨论.
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