酸的密度对硫酸盐修饰的聚碳酸超塑剂对水泥系统的作用
Yuxiang Xie1, Zixuan Zhang2, Yujie Chen1
1Guizhou Provincial Key Laboratory of Green Chemical and Clean Energy Technology, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China.
Polymers
|December 17, 2024
概括
研究人员开发了新的聚碳酸超塑剂 (PCE),以降低混凝土的高粘度. 最佳的PCE分子设计,特别是PCE-MA0.5,提高了混凝土的可加工性和动性能.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 土木工程 土木工程是指土木工程.
背景情况:
- 新鲜混凝土的高粘度,特别是高性能混凝土,带来了重大挑战.
- 抽困难和可加工性差是与粘性混凝土混合物相关的常见问题.
- 聚碳酸超塑性剂 (PCE) 是控制混凝土质的关键添加剂.
研究的目的:
- 合成和描述新的降粘性聚碳酸超塑性化剂 (PCE).
- 研究分子结构,特别是烯酸盐密度对PCE性能的影响.
- 提高水泥和混凝土的可加工性和降低粘度的能力.
主要方法:
- 合成具有硫酸组和不同烯酸密度的新型PCE.
- 合成的PCEs的表征,以确认分子结构.
- 通过吸附,流动性和泽塔电位测量评估PCE性能.
主要成果:
- 基密度较低的PCE (PCE-MA0.5) 具有最大的吸附性,最佳的流动性和最小的泽塔潜力.
- 分子结构,包括骨干刚度和吸附群密度,影响PCE的有效性.
- 引入基有效降低粘度,但可以降低吸附能力.
结论:
- 提出了一种可行的合成PCE的方法,其可加工性优越,粘度降低.
- 优化PCE分子设计是克服混凝土高粘度挑战的关键.
- 该研究提供了关于定制PCE以提高混凝土性能的见解.
更多相关视频
相关概念视频
Superplasticizers
77
Superplasticizers are advanced admixtures that enhance the workability of concrete by lowering the water content without compromising the strength of the material. These substances are highly effective water reducers, improving concrete flow, making it easier to work with, and enabling concrete to reach inaccessible areas or densely reinforced sections without mechanical vibration. The key components in superplasticizers are either sulfonated melamine or naphthalene formaldehyde condensates,...
77
Plasticizers
65
Water-reducers, or plasticizers, are chemical admixtures used in concrete to improve strength and workability. These additives reduce the water-cement ratio without compromising workability, lower the cement content while maintaining the same workability, or increase workability to assist concrete placement in inaccessible areas.
Plasticizers function by using surface-active agents to create repulsive electrostatic forces between cement particles. This dispersion enhances the concrete's...
Plasticizers function by using surface-active agents to create repulsive electrostatic forces between cement particles. This dispersion enhances the concrete's...
65
Sulfate Attack on Concrete
108
Sulfate attack on concrete is a deterioration process characterized by a whitish discoloration beginning at the edges and corners, accompanied by cracking and spalling. This phenomenon occurs when sulfates react with the components of hardened concrete, forming compounds like calcium sulfate and calcium sulfoaluminate which occupy more space than the substances they replace, causing the concrete to expand and disrupt.
Sulfates from sources like soil, groundwater, or industrial effluents...
Sulfates from sources like soil, groundwater, or industrial effluents...
108
Hydration of Cement
197
Hydration of cement is a chemical reaction between cement particles and water. This process occurs primarily through two mechanisms: through-solution and topochemical. In the through-solution process, anhydrous compounds dissolve into their constituents, hydrates form in the solution, and then precipitate from the supersaturated solution. The topochemical process involves solid-state reactions at the cement particle surface. The through-solution process dominates the topochemical process at the...
197
Acid Attack on Concrete
183
When acids come into contact with concrete, they initiate a chemical reaction that dissolves the hydrated cement paste. This process leads to softening and structural weakening of the concrete. This issue is commonly observed in environments such as chimneys, sewers, and industrial settings. The severity of the damage increases as the pH of the water interacting with the concrete drops below 6.5. In particular, a pH under 4.5 can cause significant concrete damage.
The rate at which hydrogen...
The rate at which hydrogen...
183
Additives and Fillers in Concrete
89
Additives and fillers are integral to enhancing the properties of concrete. Pozzolans and blast-furnace slag are additives or admixtures due to their reactions with calcium hydroxide released during cement hydration. Fillers, which are finely ground and similar in fineness to Portland cement, improve concrete attributes such as workability density, and reduce capillary bleeding or cracking. Some fillers possess hydraulic properties or participate in benign reactions within the cement paste.
The...
The...
89


