从化石到生物基AESO-TiO2微复合材料用于工程应用
Cristian-Dragos Varganici1, Liliana Rosu1, Dan Rosu1
1Centre of Advanced Research in Bionanoconjugates and Biopolymers, "Petru Poni" Institute of Macromolecular Chemistry, 41A Gr. Ghica-Voda Alley, 700487 Iasi, Romania.
Polymers
|December 17, 2024
概括
本研究提出了从大豆油中获得环保聚合物的绿色合成方法. 由此产生的材料用TiO2微粒增强,在各种应用中显示出更好的热稳定性和疏水性.
科学领域:
- 材料科学 材料科学 材料科学
- 绿色化学 绿色化学
- 聚合物科学 聚合物科学
背景情况:
- 越来越多的环境问题需要用可再生资源取代基于石油的材料.
- 植物油为开发各种应用的环保聚合物提供了一个可持续的来源.
研究的目的:
- 开发一种简化的绿色合成途径,用于从环氧化大豆油中获得热可固化的基质.
- 描述原始矩阵和一个包含TiO2微粒的复合材料.
主要方法:
- 福里埃变换红外光谱学 (FTIR) 技术
- 不同扫描热量计 (DSC)
- 热重力测量 (TGA) 是一种测量方法.
- 扫描电子显微镜 (SEM) 的使用
- 宽带介电光谱测量宽带介电光谱测量
- 接触角度测量 接触角度测量
主要成果:
- 使用氧化大豆油,烯酸,活性稀释剂和催化剂合成了一种无溶剂,热可固化的基质.
- 使用2%TiO2微粒填充剂的复合材料表现出增强的热稳定性 (较低的质量损失,更高的降解温度),增加的玻璃过渡温度 (-10°C vs. -20°C),改善的疏水性 (接触角度96° vs. 88°) 和优越的介电性质与原始矩阵相比.
结论:
- 开发的微复合材料具有出色的性能,适用于保护涂层,电容器,传感器和电子电路.
- 这项研究有助于绿色化学的进步和可持续材料的开发.
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