的应变歇斯底里斯和穆林斯效应与可逆牺牲网络一起火化
Rongyan Hu1, Xin Jiang1, Yaxin Chen1
1MOE Key Laboratory of Macromolecule Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310058, P. R. China. shangguan@zju.edu.cn.
Soft matter
|December 18, 2024
概括
这项研究揭示,布他-烯-维尼尔皮里丁火化物 (VPR) 中的金属协调键通过增强能量消散和可逆歇斯底里作用,显著改善自我愈合和阻尼特性. 高温有助于恢复机械和联网络特性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 机械工程 机械工程
背景情况:
- 可逆的牺牲键增强了弹性体的机械性能.
- 在具有牺牲键的火山化中,粘性弹性研究尚不发达.
研究的目的:
- 研究金属协调键对布他 - styrene-vinylpyridine硫化物 (VPR) 的机械性能的影响.
- 了解牺牲结合在能量消耗,自我愈合和阻尼中的作用.
主要方法:
- 在不同温度和延展率条件下对VPR机械性能进行系统的研究.
- 在热机械合下分析网络结构演变和粘弹性.
主要成果:
- 较低的温度和较小的菌株的较高应变率突出显示了牺牲性结合的贡献.
- 牺牲债券可以改善能量消耗和可逆歇斯底里,增强自我愈合和减缓.
- 牺牲键的高温重新排列有助于恢复机械和共价网络属性.
结论:
- 金属协调键提供了一个有前途的途径来调整非线性行为,并改善复合材料的自我愈合/缓.
- 在热机械合下了解网络演变是控制复合材料性能的关键.
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