相关实验视频
Updated: Jun 4, 2025

06:58
Zinc-Sponge Battery Electrodes that Suppress Dendrites
Published on: September 29, 2020
4.3K
单酸乙酸离子增强凝电解质,用于长期使用寿命的Zn-Air电池
Xiaoming Fan1, Yanchun Xie1, Yucong Jiao1
1State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China.
ACS nano
|December 18, 2024
概括
工程水凝电解质防止了柔性气电池 (FZAB) 的副作用和水损失,在各种温度下显著延长了它们的使用寿命.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 聚合物科学 聚合物科学
背景情况:
- 灵活的Zn-空气电池 (FZAB) 提供了高安全性,但受到副产品的形成和水分的不良保留的影响.
- 这些局限性阻碍了它们在各种场景中的实际应用.
研究的目的:
- 为FZABs设计一种新的水凝电解质 (GAHE).
- 为了应对副产品形成和水性电解质中保持水分的挑战.
主要方法:
- 在现场聚合烯胺 (AM) 在酸 (CGG) 和酸盐溶液中的聚合.
- 使用乙酸离子 (OAc-) 来控制pH值,并通过键增强水分保留.
主要成果:
- GAHE电解质保持中性pH值,抑制了副作用的发生.
- 乙离子促进了快速离子扩散,抑制了水的活性,改善了水的保留.
- 在现场的聚合产生了一种机械强大的电解质,具有出色的界面稳定性.
- 使用GAHE的FZAB在室温下达到2050小时,在-35°C下达到2940小时的寿命.
结论:
- 开发的GAHE水凝电解质有效抑制了副作用,并增强了FZABs中的水留.
- 这项工作为灵活的储能设备设计具有更好的稳定性和寿命的水性电解质提供了新的策略.
相关概念视频
Ions as Acids and Bases
23.6K
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
23.6K
Polyprotic Acids
29.0K
Acids are classified by the number of protons per molecule that they can give up in a reaction. Acids such as HCl, HNO3, and HCN that contain one ionizable hydrogen atom in each molecule are called monoprotic acids. Their reactions with water are:
29.0K
Batteries and Fuel Cells
27.0K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.0K
Ion Exchange
546
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
546
Standard Electrode Potentials
43.4K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
43.4K
Diazonium Group Substitution: –OH and –H
2.7K
Nitrous acid, a weak acid, is prepared in situ via the reaction of sodium nitrite with a strong acid under cold conditions. This nitrous acid prepared in situ reacts with primary arylamines to form arenediazonium salts. Such reactions are known as diazotization reactions. As shown in Figure 1, the formation of arenediazonium salts begins with the decomposition of nitrous acid in an acidic solution to give nitrosonium ions.
2.7K

