从堆肥中获得的溶解有机物质的光化学反应
Ziling Xiao1, Jingyan Zhang1, Yilang Qin1
1College of Natural Resources and Environment, Northwest A&F University, Yangling 712100, PR China.
The Science of the total environment
|December 19, 2024
概括
堆肥衍生的溶解有机物 (DOM) 经历光化学变化. 牛DOM (CDOM) 显示出较大的分子量减少,并且比猪DOM (PDOM) 产生了更多的活性氧物种.
科学领域:
- 环境化学环境化学
- 摄影化学的使用.
- 土壤科学 土壤科学
背景情况:
- 堆肥应用对土壤健康至关重要,引入影响生态系统的溶解有机物 (DOM).
- 来自堆肥的DOM (DOMCOM) 的光化学行为尚未得到充分理解,这阻碍了对其环境命运的预测.
- 了解DOMCOM光化学对于评估其在碳循环和污染物运输中的作用至关重要.
研究的目的:
- 研究来自牛 (CDOM) 和猪 (PDOM) 的DOM的光化学转化和光活性.
- 为了比较CDOM和PDOM在紫外线照射下的分子量变化,化和活性氧物种生成.
- 阐明CDOM和PDOM中光分量的不同光化学反应.
主要方法:
- 对CDOM和PDOM进行紫外线照射.
- 使用尺寸排除色谱分析分子重量分布.
- 二维相关谱 (2D-COS) 分析光.
- 三重 DOM (3DOM*),单一氧 (1O2) 和基 (•OH) 的量化.
主要成果:
- 与PDOM相比,CDOM具有更高的初始分子量,芳香度和度.
- 紫外线照射导致显著的光漂白和光化,使CDOM分子量减少23.68%,PDOM分子量减少3.82%.
- 富尔维克样光分数首先对辐射做出反应,其次是蛋白质样和微生物样分数,CDOM和PDOM的趋势明显.
- 与PDOM相比,CDOM产生了3DOM*,1O2和•OH的度更高.
结论:
- 来自堆肥的DOM经历了显著的光化学变化,而奶牛便的DOM更容易受到分子重量减少的影响.
- DOMCOM的光化学反应受其成分的影响,特别是类物质.
- 紫外线诱导的活性氧物种产生在CDOM和PDOM之间有所不同,影响它们的环境作用.
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