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在高盐度和高温度条件下提高离子表面活性剂的水性稳定性,使用SiO2纳米粒子2
Mohammed H Alyousef1, Muhammad Shahzad Kamal1,2, Mobeen Murtaza2
1Department of Petroleum Engineering, King Fahd University of Petroleum & Minerals, Dhahran 34464, Saudi Arabia.
ACS omega
|December 23, 2024
概括
二氧化纳米颗粒在高盐度条件下稳定阴离子表面活性物,用于化学增强的石油回收. 这种新的方法可以防止降水和聚合,为极端环境提供了具有成本效益的解决方案.
科学领域:
- 石油工程是石油工程中的一个.
- 材料科学 材料科学 材料科学
- 合体和表面化学
背景情况:
- 无离子表面活性剂对于化学增强石油回收 (cEOR) 至关重要,但在高盐分盐中会破坏稳定.
- 传统的稳定方法,如表面活性剂,在兼容性和成本方面都有局限性.
- 需要强大的解决方案来维持在恶劣的油田条件下表面活性剂的性能.
研究的目的:
- 开发一种新的方法,在极端盐度条件下增强阳离子表面活性剂的稳定性.
- 研究二氧化 (SiO2) 纳米颗粒在防止表面活性剂沉和聚合方面的有效性.
- 评估纳米粒子表面活性剂配方在高盐度和高温度条件下的性能.
主要方法:
- 含有不同度SiO2纳米颗粒的离子表面活性剂的配方.
- 使用度,泽塔潜力 (ZP) 和水力动力直径 (HDD) 测量进行稳定性评估.
- 评估该配方在盐水中的性能,盐度高达57,000ppm,温度为70°C.
主要成果:
- 一个最佳的SiO2纳米颗粒度 (0.01重量%) 显著改善了二硫酸盐 (SDS) 的稳定性.
- 该配方表现出稳定性,在极端盐水中7天内没有观察到聚合或沉.
- 高绝对ZP值 (>25mV),小型HDD (~37nm) 和一致的度证实了配方的稳定性和分散性.
结论:
- 纳入SiO2纳米颗粒是一种有效的策略,可以在高盐度和高温环境中增强阳离子表面活性剂的稳定性.
- 这种基于纳米粒子的方法为化学增强的石油回收提供了具有成本效益和可持续性的进步.
- 该研究提供了一个强大的解决方案,以克服传统表面活性剂在CEOR应用中的盐耐受性限制.
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