氧度对挥发性降水和关键点燃点的影响
Yulong Li1,2,3, Xuechao Su2,3, Chaosheng Wang2,3
1Engineering College, Guangzhou College of Technology and Business, Guangzhou Business College, No.23, Sanhua Road, Fanhu Economic Development Zone, Leping Town, Sanshui District, Foshan City, Guangdong Province 510850, P. R. China.
煤的临界点火温度随着样本质量的增加而显著下降. 较高的氧气度增强了煤炭热解,影响了点火行为.
科学领域:
- 燃烧科学 燃烧科学
- 煤炭化学 煤炭化学
- 材料科学 材料科学 材料科学
背景情况:
- 煤炭点燃是采矿安全和能源利用的关键因素.
- 了解氧气度和样品质量对煤炭点火的影响对于防止自发燃烧至关重要.
研究的目的:
- 为了研究氧气度对煤点火的影响.
- 为了确定样品质量和临界点火温度之间的关系.
- 为了分析氧化过程中煤炭的化学变化.
主要方法:
- 大规模的氧化实验,使用不同度和温度的氧气.
- 使用形式提取氧化煤.
- 通过气相色谱-质谱法 (GC-MS) 分析液体提取物.
- 使用富里埃变换红外光谱法 (FTIR) 进行提取的氧化煤的表征.
主要成果:
- 由于样品质量从5g增加到300g,煤的临界点火点下降了229.4°C.
- 增加的氧气度在恒定温度下增强了煤热解.
- 煤炭氧化活性最初下降,然后随着温度的上升而增加.
- 175°C以上的以太键分解与煤层点火有关.
结论:
- 样品质量和氧气度是影响煤点火的关键因素.
- FTIR和GC-MS分析揭示了与煤炭氧化和点火有关的化学转变.
- 这些发现提供了关于煤层火灾预防和燃烧管理的见解.
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