通过氧化中缺陷状态介导的的三重激发刺激敏感化
Narumi Nagaya1,2, Alexandra Alexiu3, Collin F Perkinson1,3
1Research Laboratory of Electronics, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA, 02139, USA.
Advanced materials (Deerfield Beach, Fla.)
|December 23, 2024
概括
在太阳能电池中,单点刺激裂变由含的氧化介层增强. 这些间层通过带边状态促进三重激子传输,提高太阳能电池的效率.
科学领域:
- 材料科学 材料科学 材料科学
- 太阳能光伏发电是如何实现的
- 量子化学 是一个量子化学.
背景情况:
- 单点激发裂变 (SEF) 提供了一条超越太阳能电池中Shockley-Queisser极限的途径.
- 在和SEF材料之间的界面上,高效的能量传输至关重要,但人们对其了解甚少.
- 哈夫氧化介层正在研究它们在调解三重激素转移中的作用.
研究的目的:
- 为了研究氧化介层成分对三重激励子转移到的影响.
- 为了阐明控制-四基接口能量合的机制.
- 确定优化间层以提高太阳能电池性能的策略.
主要方法:
- 磁场依赖的光发光 (PL) 测量.
- 密度函数理论 (DFT) 的计算.
- 对氧化间层组成的分析,重点关注含量.
主要成果:
- 氧化海中间层单独不会通过三重激子使敏感.
- 在 hafnium oxynitride 介层中含量增加与增强的三重激素敏感性相关.
- DFT计算显示,带边缘附近的诱导的缺陷介于三重传输.
- 一些缺陷会导致光发光的灭,原因是有害的中间隙状态.
结论:
- 带边状态是由丰富的氧化中缺陷引入的,可以有效地调解三重激子转移.
- 为三重激子转移提出了一种连续的电荷转移机制.
- 精确控制层间成分是优化太阳能电池SEF的关键.
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