使用PANI/石墨/比斯穆特化物复合材料制造的柔性热电发电机的制造和特性
Yoshitha P A1, Manasa R Shankar1, A N Prabhu1
1Department of Physics, Manipal Institute of Technology, Manipal Academy of Higher Education Manipal 576104 Karnataka India ashwatha.prabhu@manipal.edu.
RSC advances
|December 24, 2024
概括
灵活的热电发电机是使用聚氨,石墨和胺化物复合材料制成的. 优化的比率显著提高了性能,为低温能源采集提供了有前途的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术 纳米技术
背景情况:
- 灵活的热电发电机 (FTEG) 对于低温能源采集至关重要.
- 导电聚合物和石墨为FTEG提供了独特的热电特性.
- 幕印刷使这些灵活的设备的可扩展制造成为可能.
研究的目的:
- 开发使用聚氨酸-石墨烯-比斯穆特化物复合材料的新型FTEG.
- 为了优化复合材料的比率,以提高热电性能.
- 调查材料组成对设备效率的影响.
主要方法:
- 通过丝网印刷制造灵活的热电发电机.
- 制备不同比例的聚氨酸-石墨复合材料和1%重量比斯穆特化物.
- 热电性质的表征,包括带隙,载体流动性,Seebeck系数和功率因子.
主要成果:
- 优化的聚氨酸:石墨比率 (1:2) 与1%重量%的比斯穆特化物产生了优越的性能.
- 带间距从2.90 eV (聚氨) 减少到1.05 eV (复合材料).
- 航母的移动性从0.12增加到0.41 cm2 V-1 s-1.
- 在90°C差距下实现的最大西贝克系数 (39.14μV K-1),功率系数 (0.29nW m-2 K-2) 和输出功率 (0.58nW).
- 性能增强是纯聚亚尼林器件的4.0,5.8和6.1倍.
结论:
- 开发的复合FTEG显示了显著提高的热电性能.
- 优化组合是提高载波机动性的关键,并减少频段差距,以实现高效的能源转换.
- 这些发现为先进的灵活热电能收集解决方案铺平了道路.
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