在现场转换人工丰富质子的外到无机的面膜,转换为稳定的单晶丰富的阴极
Haoyu Xue1, Yongzhi Liang1, Yuxiang Huang2
1School of Advanced Materials, Peking University Shenzhen Graduate School, Shenzhen, 518055, China.
Advanced materials (Deerfield Beach, Fla.)
|December 26, 2024
概括
在富含的正极单晶上,一种新的富含质子的外,产生了一种保护性的无机遮剂. 这提高了先进的电池的电化学稳定性和性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 单晶高氧化物阴极提供结构完整性,但由于其高面积比而遭受表面退化.
- 表面降解严重影响这些先进的阴极材料的电化学性能和长期稳定性.
研究的目的:
- 为了提高富含的LiNi0.92Co0.06Mn0.02O2单晶阴极的稳定性和电化学性能.
- 开发一种现场方法,在阴极表面上制造一种保护性无机遮剂层.
主要方法:
- 在富含的单晶阴极上引入人工富含质子 (二碳酸) 的外.
- 在第一个充电周期期间,利用LiPF6电解质在现场电化学转换丰富的质子外.
- 在阴极表面形成一个亚纳米粒子密度高的无机遮剂 (LiF和Li3PO4) .
主要成果:
- 在现场形成的紧型纳米F-&P-maskant有效地保护阴极免受电解质攻击.
- 在长期循环过程中,阴极颗粒的表面稳定性得到了显著改善.
- 在4.5V (半电池) 100个循环后达到95%的容量保留,在800个循环后达到83% (全电池).
结论:
- 使用富含质子外的策略使得保护性无机层在现场形成.
- 这种表面修改方法提高了高单晶阴极的稳定性和循环性能.
- 展示了一种可行的方法,用于重建先进电池应用的保护层.
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