在GdDyHoErTm高合金中,多个磁相转换和巨大的制冷能力
Yanyan Shao1, Siyu Cheng1, Mingxiao Zhang2
1School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
ACS applied materials & interfaces
|December 28, 2024
概括
磁热高合金 (HEAs) 显示出磁性制冷的前景. 这项研究揭示了GdDyHoErTm HEAs表现出多个磁转换,实现桌式磁热效应以实现高效的冷却.
科学领域:
- 材料科学 材料科学 材料科学
- 热力学是一种热力学.
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 磁热高合金 (HEAs) 正在探索磁性制冷,因为它们的工作温度范围广泛,制冷剂容量大.
- 稀土元素提供了各种各样的磁性特性,对于先进的磁热材料至关重要.
研究的目的:
- 为了研究等原子GdDyHoErTm HEAs的结构性,磁性和磁热性质.
- 评估这些稀土高温电站在低温磁性制冷应用中的潜力.
主要方法:
- 对等原子GdDyHoErTm HEAs的合成和表征.
- 使用X射线衍射分析结构性质的分析.
- 在应用磁场下测量磁性和磁热性质.
主要成果:
- 造合金表现出一个单一的六角相,具有复杂的磁性.
- 在广泛的温度范围内 (27-175 K) 观察到多个磁相过渡.
- 实现了表式磁热效应,在5T时最大磁变化为7.5J/kgK.
结论:
- GdDyHoErTm HEA显示出巨大的制冷剂容量 (923 J/kg) 和相对冷却功率 (1110 J/kg).
- 观察到的多个磁相转换有助于增强磁热性能.
- 这项研究为开发高性能磁热材料为冷磁性制冷铺平了道路.
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