在纳米尺度上取决于尺寸的湿接触角度,由等角表面和张力表面定义
Sergii Burian1,2, Yevhenii Shportun3, Andriy Yaroshchuk4,5
1Faculty of Physics, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska Street, Kyiv, 01601, Ukraine. burian_sergii@knu.ua.
Scientific reports
|December 29, 2024
概括
调查纳米级湿,这项研究揭示了圆柱形纳米滴的等角和张力表面之间的接触角度测量的显著差异. 这些差异凸显了界面科学中表面定义的重要性.
科学领域:
- 接口和表面科学 接口和表面科学
- 在纳米尺度流体动力学.
- 物理化学 物理化学
背景情况:
- 湿现象在表面科学中至关重要,接触角度作为一个关键的指标.
- 由于接触角度歇斯底里和纳米级接口复杂性,量化湿是具有挑战性的.
- 定义了该项目的定义.
- 分隔面的表面是分隔面.
- 在纳米尺度上是模两可的.
研究的目的:
- 通过分子动力学模拟来研究纳米级滴和膜的湿化动力学.
- 分析密度和张力张量分布以确定相关的表面.
- 根据不同的表面定义,量化接触角计算中的差异.
主要方法:
- 一个圆柱形纳米滴和纳米膜的分子动力学模拟.
- 微观密度分布图的分析.
- 对于张力张量分布的吉布斯框架的应用.
主要成果:
- 在液体-气体和液体-固体接口上确定了等极和张力表面.
- 观察到纳米滴在等等和张力表面之间的平衡接触角度有超过10%的差异.
- 证明了湿接触角度对纳米滴半径的依赖性,在更小的半径上差异越来越大.
结论:
- 选择的表面定义显著影响纳米级湿角度的计算.
- 均角和张力表面产生不同的接触角度,特别是较小的圆柱形纳米滴.
- 在纳米尺度上的湿行为对滴滴几何和表面定义敏感.
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