制备四级氨基硫酸改性抗UV聚氨及其在皮革染料中的应用
Yongxiang Zhou1, Changlong Yuan2, Qi Zhang3
1College of Bioresources Chemical & Materials Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China; National Demonstration Center for Experimental Light Chemistry Engineering Education, Xi'an 710021, China; Xi'an Key Laboratory of Green Chemicals and Functional Materials, Xi'an 710021, China.
International journal of biological macromolecules
|December 29, 2024
概括
这项研究开发了一种抗UV复合材料,使用修改后的硫酸和聚氨来改善皮革.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 织品化学 织品化学
背景情况:
- 阴阳性水性聚氨 (CWPU) 增强皮革染色,但在紫外线下降解.
- 用CWPU处理的皮革在长时间暴露在阳光下会色,变硬和裂.
研究的目的:
- 开发一种抗紫外线的复合材料,用于皮革处理.
- 为了提高皮革的耐用性和色彩稳定性.
- 为了提高经过处理的皮革的整体质量和寿命.
主要方法:
- 通过四级化制备的四级氨基硫酸盐 (QLS).
- 合成的抗紫外线的阳性水性聚氨 (UVCWPU).
- 通过混合改性聚氨和基硫酸盐,创建了一个QLS/UVCWPU复合物.
主要成果:
- 优化了QLS修改,具有7:1的CHPTMAC与LS比率,达到6.65和4.32%的N含量的同电点.
- 通过QLS/UVCWPU处理,皮革染料的吸收率提高到97.3%,K/S值提高到28.51.
- 改善了干擦的颜色稳定性到5级和湿擦到3级,同时增强了紫外线抵抗力和抗菌特性.
结论:
- 开发的QLS/UVCWPU复合材料有效地提高了皮革的染色速率,色彩稳定性和抗UV的性能.
- 这种新的复合材料减轻了紫外线的退化,延长了皮革的寿命并保持了皮革的美学质量.
- 增强的性能表明在皮革装饰和保护中具有广泛的应用.
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