键在基振动光谱中的蓝移是由键几何学和动力学决定的

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Updated: May 7, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

Published on: July 27, 2022

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Jacob M Kirsh1, Jacek Kozuch2,3

  • 1Department of Chemistry, Stanford University, Stanford, California 94305-5012, United States.

JACS Au
|December 30, 2024
PubMed
概括

一个新的模型解释了在振动斯塔克效应 (VSE) 光谱中用烯探针观察到的异常键 (HB) 蓝移. 这个框架解释了HB的几何和动态,改善了各种化学系统的预测.

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