在热力机械合下对煤炭自燃特性进行研究
Ji Wu1, Zongxiang Li2,3, Shuoran Huang2
1College of Safety Science and Engineering, Liaoning Technical University, Fuxin, 123000, Liaoning, China. 15566103225@163.com.
Scientific reports
|December 31, 2024
概括
更深的煤矿开采会增加地面温度和压力,改变煤炭结构并增强自燃. 这项研究揭示了热和机械合如何影响煤炭.
科学领域:
- 地质地质地质地质地质地
- 采矿工程 采矿工程 采矿工程
- 煤炭科学 煤炭科学
背景情况:
- 越来越深的采矿深度会提高地面温度和压力.
- 这影响了煤炭裂变的发展和自燃.
- 炭煤特别容易受到这些变化的影响.
研究的目的:
- 研究孔隙结构和含氧的功能群对煤炭自燃的影响.
- 分析这些影响背后的物理和化学机制.
- 了解热力和机械合在石中的作用.
主要方法:
- 扫描电子显微镜 (SEM) 用于微观结构分析.
- 低温N2吸附以表征孔隙结构.
- 用温度编程的实验来评估燃烧特性.
- 红外光谱测量以确定功能组含量.
主要成果:
- 热和机械合增强了孔隙断裂连接性和微断裂规模.
- 煤炭氧化增加,导致标志性燃烧气体的生产率提高.
- 含有芳香碳化合物,含有氧的功能组和酸碳化合物的含量增加.
结论:
- 热和机械合显著促进了煤炭的自燃.
- 煤炭结构,温度,压力和煤炭氧反应的变化是关键因素.
- 这些发现为防止多场合煤自燃 (CSC) 提供了理论基础.
相关概念视频
Enthalpy and Heat of Reaction
8.2K
Combustion, commonly known as burning, is a reaction in which a substance reacts with an oxidizing agent, which in most cases is molecular oxygen, to liberate energy in the form of heat, light, or sound. The heat of combustion is also known as the enthalpy of combustion. The energy released when one mole of a substance undergoes complete combustion at constant pressure is called molar heat of combustion. Combustion reactions are exothermic; that is, they release energy, and their ΔH sign...
8.2K
Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes
6.2K
The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
6.2K
Constant Volume Calorimetry
26.7K
Calorimeters are useful to determine the heat released or absorbed by a chemical reaction. Coffee cup calorimeters are designed to operate at constant (atmospheric) pressure and are convenient to measure heat flow (or enthalpy change) accompanying processes that occur in solution at constant pressure. A different type of calorimeter that operates at constant volume, colloquially known as a bomb calorimeter, is used to measure the energy produced by reactions that yield large amounts of heat and...
26.7K
Spontaneity
22.8K
A spontaneous process is one that occurs naturally under certain conditions. A nonspontaneous process, on the other hand, will not take place unless it is “driven” by the continual input of energy from an external source. Processes have a natural tendency to occur in one direction under a given set of conditions. Water will naturally flow downhill (spontaneous process), but uphill flow (nonspontaneous process) requires outside intervention such as the use of a pump. Iron exposed to...
22.8K
Mechanisms of Heat Transfer
85
Heat transfer between the human body and its environment occurs through four main mechanisms: conduction, convection, radiation, and evaporation.
Conduction, accounting for approximately 3% of body heat loss at rest, is the process of exchanging heat between molecules of two materials in direct contact. This can result in both heat loss and gain. For instance, when the body is submerged in water, which conducts heat 20 times more effectively than air, it can either lose or gain significant...
Conduction, accounting for approximately 3% of body heat loss at rest, is the process of exchanging heat between molecules of two materials in direct contact. This can result in both heat loss and gain. For instance, when the body is submerged in water, which conducts heat 20 times more effectively than air, it can either lose or gain significant...
85
Mechanism of heat transfer
1.1K
Understanding heat transfer mechanisms is essential for understanding how our bodies maintain balance in different environmental conditions. When the environment is thermoneutral, the body is in a state of balance, neither using nor releasing energy to maintain its core temperature. However, when the environment is not thermoneutral, the body employs four heat transfer mechanisms to maintain homeostasis: conduction, convection, evaporation, and radiation. These mechanisms facilitate heat...
1.1K


