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Updated: May 7, 2025

Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
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Published on: August 16, 2018

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网状结晶多孔材料用于不对称的异质催化

Xing Han1, Weiwei Li1, Bolinyishi Yang1

  • 1School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China.

Advanced materials (Deerfield Beach, Fla.)
|December 31, 2024
PubMed
概括

状金属有机框架 (MOF) 和共价有机框架 (COF) 提供了对选择性催化物的精确控制. 网状化学提升了这些晶体多孔材料,以实现高效的不对称合成.

关键词:
不对称的催化剂共价有机框架是共价有机框架.金属的有机框架.网状化学 网状化学

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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