经过化/三乙烯胺改性作为一种高效的吸附剂,用于选择性吸附离子染料
Kriti1, Kiran Kumar1, Ghanshyam S Chauhan1
1Department of Chemistry, Himachal Pradesh University, Summerhill, Shimla, Himachal Pradesh 171005, India.
International journal of biological macromolecules
|January 1, 2025
概括
研究人员开发了一种新型的阴离子吸附剂 (TPsy),用于有效地去除MO和CR等离子染料. 这种可持续材料实现了高吸附能力和可回收性,为染料废水处理提供了有希望的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 绿色化学 绿色化学
背景情况:
- 开发可持续吸附剂对于环境修复至关重要.
- 普西是一种天然的阳离子多糖体,需要进行修改以获得高效的阳离子染料吸附.
- 表面电荷修改是提高吸附剂性能的一个关键策略.
研究的目的:
- 从天然中合成一种新型的基离子基吸附剂 (TPsy).
- 评估TPsy在吸附阳离子染料 (MO和CR) 的效率.
- 研究TPsy的吸附机制,动力学和再生能力.
主要方法:
- 两步合成:用psyllium环氧化,然后用triethylamine进行四度化.
- 使用甲基色 (MO) 和刚果红色 (CR) 作为离子染料的吸附实验.
- 吸附动力学 (伪二次) 和异温的分析 (Langmuir).
主要成果:
- 合成的TPsy表现出来自阴离子的阴离子表面电荷 (PZC = 6.23) (PZC = 2.25).
- 在70分钟内,MO的最大吸附百分比为93.94%和CR的最大吸附百分比为94.44%.
- 获得了MO的223.71 mg/g和CR的260.41 mg/g的高吸附能力 (q_m).
- 其他Psy在12个吸附-脱附周期中表现出极好的再生能力.
结论:
- 的四度化有效地将其转化为离子染料的高效的阴离子吸附剂.
- TPsy吸附剂显示出可持续和经济有效地从废水中去除染料的巨大潜力.
- 静电吸引和键是驱动吸附过程的关键机制.
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