有机离子塑料晶体具有可持续冷却的巨大热量效应
Samantha L Piper1, Leena Melag1, Mega Kar1
1Institute for Frontier Materials, Deakin University, Burwood, VIC, Australia.
概括
有机离子塑料晶体 (OIPC) 对节能冷却具有前景. 这些新的巴洛卡路里 (BC) 材料具有很大的变化和可调节的特性,用于可持续的制冷应用.
科学领域:
- 材料科学
- 热力学
- 固态物理
背景情况:
- 巴罗卡洛里 (BC) 材料通过压力诱导的相位过渡实现了节能制冷.
- 现有的BC材料往往缺乏适合家庭应用的过渡温度.
研究的目的:
- 引入有机离子塑料晶体 (OIPC) 作为一种新型的BC材料.
- 研究OIPC在可持续冷却技术方面的潜力.
主要方法:
- 对OIPC的综合和描述.
- 测量热量效应,包括过渡温度和变化.
- 通过对离子组件的结构修改调整BC特性.
主要成果:
- 在OIPC中表现出下环境过渡温度.
- 证明了从92到240J/kg·K的巨大变化.
- 观察到高压敏感度,高达23.7K/kbar.
- 通过离子结构修改实现可调节的BC反应.
结论:
- OIPC代表了一个有前途的新类型的热量材料.
- 它们的调节性质和显著的热量效应使它们成为有效和可持续的冷却.
- OIPC为下一代制冷和空调技术提供了可行的途径.
相关概念视频
Recrystallization: Solid–Solution Equilibria
983
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
983
Crystal Growth: Principles of Crystallization
1.4K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
1.4K
Molecular and Ionic Solids
16.5K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
16.5K
Ionic Crystal Structures
13.9K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
13.9K
Ion Exchange
387
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
387
Precipitation of Ions
27.3K
Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
27.3K


