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Updated: Jun 4, 2025

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
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Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

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用H2S/Thiol调解和的酸盐在固态中的酸盐减少

Garik G Martirosyan1, Astghik A Hovhannisyan1, Lusine S Harutyunyan1

  • 1The Scientific Technological Centre of Organic and Pharmaceutical Chemistry NAS RA, Molecule Structure Research Centre, 26 Azatutyan Av., Yerevan 0014, Armenia.

Inorganic chemistry
|January 3, 2025
PubMed
概括

研究人员探索了金属蛋白如何将酸盐转化为酸盐,这是对缺氧损伤的关键保护机制. 利用仿生模型,他们确定了这种重要的生物转变的新型中间体和途径.

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Preparation and Reactions of Thiols02:33

Preparation and Reactions of Thiols

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Though catalytic hydrogenation can reduce nitrobenzenes, the reduction is nonselective in the presence of other functional groups. For instance, if nitrobenzene contains an aldehyde group,...
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Nitriles are reduced to amines in the presence of strong reducing agents like lithium aluminum hydride through a typical nucleophilic acyl substitution. The reaction requires two equivalents of the reducing agent. The reducing agent acts as a source of hydride ions.
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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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