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Updated: Jun 4, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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(III) 酸盐和 (IV) 基酸盐作为轻度,选择性硫酸化的催化剂

Calvin Samuel1, Tokala Navaneetha1, Junaid Ali1

  • 1School of Chemistry, University of Hyderabad, Hyderabad500046, India.

Inorganic chemistry
|January 3, 2025
PubMed
概括

两种新型的 (Ce) 氧基聚合物,一种Ce (III) 酸盐和一种Ce (IV) 酸盐,被合成和特征化. 这些集群在有毒硫化物硫化和氧化过程中表现出催化活性.

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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The Wittig reaction, which converts aldehydes or ketones to alkenes using phosphorus ylides, proceeds through a nucleophilic addition‒elimination process.
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