表面复杂性和包装床大规模运输模型使酸盐和酸盐去除吸附剂设计成为可能
Emily Briese1, Ken Niimi1, Annika Hjelmstad2
1School of Sustainable Engineering & the Built Environment, Arizona State University, Tempe, Arizona 85287, United States of America.
概括
这项研究将表面复合模型 (SCM) 与毛孔表面扩散模型 (PSDM) 联系起来,以预测水中的oxo-anion去除. 组合模型准确地预测了污染物的突破,并指导了为公共健康设计更好的吸水剂.
科学领域:
- 环境化学环境化学
- 水处理技术水处理技术
- 吸附科学 吸附科学
背景情况:
- 饮用水中的金属氧化,如酸盐,对人类健康构成重大风险.
- 了解竞争性吸附和突破对于有效的净水系统至关重要.
- 连续流量包装床吸附系统需要精确的建模来优化过程.
研究的目的:
- 开发和验证一种结合式建模方法,将表面复杂化模型 (SCMs) 和孔隙表面扩散模型 (PSDM) 联系起来.
- 预测包装床吸附系统中单个和混合的oxo-anions的行为.
- 评估吸附介质特性和水的化学成分,以优化水处理系统.
主要方法:
- 链接平衡表面复合模型 (SCM) 与孔隙表面扩散模型 (PSDM).
- 用两个商业吸附剂的吸附等温数据对模型进行参数化.
- 使用单溶液和双溶液列突破数据验证了SCM+PSDM,包括染色学位移.
主要成果:
- SCM+PSDM准确预测了酸盐和酸盐的吸附同热度和柱突破曲线.
- 商业吸附剂的确定表面和孔隙扩散率 (例如,表面:3.0-3.5 x10-12 cm2 / s,孔隙:1.1-0.8 x10-6 cm2 / s).
- 在模拟表明,增强吸附剂表面反应性对使用点 (POU) 系统比单独的孔隙设计更有利.
结论:
- 集成的SCM+PSDM是一个强大的工具,用于预测包装床中的oxo-anion吸附和突破.
- 对于POU应用的吸附剂设计应优先考虑表面结合亲和性和反应性.
- 对于市政系统来说,控制粒子内多孔性 (εp) 是提高质量转移区性能的关键.
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