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Updated: Jun 3, 2025

A Protocol for Safe Lithiation Reactions Using Organolithium Reagents
09:45

A Protocol for Safe Lithiation Reactions Using Organolithium Reagents

Published on: November 12, 2016

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在和性土离子上选择性提取,通过协同溶剂提取

Stijn Raiguel1, Laura Van Bogaert1, Tim Balcaen1

  • 1KU Leuven, Department of Chemistry Celestijnenlaan 200F P.O. box 2404 B-3001 Leuven Belgium stijn.raiguel@kuleuven.be.

Green chemistry : an international journal and green chemistry resource : GC
|January 6, 2025
PubMed
概括

一个新的协同溶剂提取系统有效地将从盐水中分离出来. 这种方法使用了选择性联体和离子交换器,改善了从地热盐水等具有挑战性的来源中提升的回收.

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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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