高分子量有机物作为在化过程中有毒化消毒副产品的前体
Wenyuan Yang1,2,3, Tom Bond4, Chao Fang1,5
1State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China.
Environmental science & technology
|January 7, 2025
概括
饮用水中的高分子量有机物是有毒化消毒副产品 (I-DBPs) 的关键前体. 了解这些前体对于确保安全饮用水和管理I-DBP风险至关重要.
科学领域:
- 环境化学环境化学
- 水处理 处理水的方法
- 毒理学 毒理学 毒理学
背景情况:
- 化消毒副产品 (I-DBPs) 由于其高毒性,对饮用水安全构成重大风险.
- 毒性I-DBPs的前体和形成途径仍然不明,这阻碍了有效的风险管理.
研究的目的:
- 为了确定天然有机物质的前体分数,负责在水消毒过程中形成有毒的I-DBPs.
- 描述已识别的I-DBPs并评估它们相对于监管消毒副产品的毒性.
主要方法:
- 通过超过方法按分子量分化天然有机物质.
- 分子的消毒,然后对细胞毒性和基因毒性进行评估.
- 使用FT-ICR MS和Orbitrap MS分析I-DBP形成,并通过化学标准进行确认.
主要成果:
- 10-100kDa的有机物质分量在化过程中显示出与酸的最高毒性和反应性.
- 在饮用水中检测到四种新型I-DBPs,其中包括两种以前未被识别的饮用水.
- 确定的I-DBPs比受管制的化和化DBPs有2-3个数量级的毒性.
结论:
- 高分子量有机物 (10-100 kDa) 是有毒I-DBPs的主要前体.
- 需要进一步的研究来解决与饮用水中I-DBP形成和控制相关的挑战.
- 这项研究为I-DBPs的前体和毒性提供了关键的见解,有助于制定更安全的水处理策略.
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