聚乳酸/聚基酸/聚乙烯酸- (co-adipate) 二元和三元混合物的热力学和机械分析
Alisa Sabalina1, Oskars Platnieks1, Gerda Gaidukova1
1Institute of Chemistry and Chemical Technology, Faculty of Natural Sciences and Technology, Riga Technical University P. Valdena 3 LV-1048 Riga Latvia oskars.platnieks_1@rtu.lv sergejs.gaidukovs@rtu.lv.
RSC advances
|January 7, 2025
概括
这项研究探讨了可生物降解的聚合物混合物,发现聚丁酸盐-共合物 (PBSA) 增强了聚乳酸 (PLA) 和聚基酸盐 (PHA) 混合物. PBSA提高了柔性和冲击强度,显示了可持续生物塑料的前景.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 可持续材料 可持续材料
背景情况:
- 来自可再生资源的可生物降解聚合物对于可持续性至关重要.
- 聚合物混合物比共聚合物提供了更好的机械性能和成本效益.
- 聚乳酸 (PLA),聚乙烯糖酸联合酸 (PBSA) 和聚氧酸 (PHA) 是关键的生物聚合物.
研究的目的:
- 研究PLA,PBSA和PHA的二进制和三进制混合物的特性.
- 评估PBSA对PLA和PHA混合物的机械性能和兼容性的影响.
- 探索这些生物聚混合物的各种应用潜力.
主要方法:
- 准备和表征九个二元和四个三元生物聚合物混合物.
- 使用扫描电子显微镜 (隐含) 等技术进行形态分析.
- 机械测试,包括拉伸延伸和冲击强度测量.
- 动态机械分析 (DMA) 和热量测量分析 (DSC) 用于测量热性能.
主要成果:
- 大多数混合物在它们的形态学中都表现出球形的包含.
- 添加PBSA显著增加了拉伸延伸和冲击强度.
- 聚烯/PBSA混合物 (30/70重量%) 在破裂时显示出172%的令人印象深刻的延长.
- PBSA与PLA的相容性比与PHA的相容性更好.
- 玻璃过渡温度在很大程度上不受PBSA二元混合物的组成的影响,而结晶行为则发生了变化.
结论:
- 生物聚合物的混合物,特别是包含PBSA的混合物,可以根据特定的机械性能量身定制.
- PBSA是增强基于PLA和PHA的生物塑料性能的一个有前途的成分.
- 这些开发的生物塑料有可能用于汽车,农业,食品包装和形状记忆材料.
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