铜漂浮尾链在基于热带石和飞的地聚合物材料中的利用
Marija Štulović1, Dragana Radovanović1, Jelena Dikić1
1Innovation Center of the Faculty of Technology and Metallurgy in Belgrade Ltd., University of Belgrade, Karnegijeva 4, 11120 Belgrade, Serbia.
Materials (Basel, Switzerland)
|January 8, 2025
概括
地质聚合有效地在可持续材料中重复使用铜漂浮尾矿 (FT). 使用50%FTs的飞灰基地质聚合物实现了高强度,证明了废物回收利用潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 地质化学 地质化学
背景情况:
- 铜漂浮尾矿 (FTs) 由于浸和灰尘而带来环境风险.
- 目前的处置方法,如倾销,是不可持续的.
- FT含有高酸含量,提供了重复使用的潜力.
研究的目的:
- 为了评估FT的地质聚合,以实现可持续的材料生产.
- 研究FT含量对地质聚合物特性的影响.
- 为了评估地质聚合物矩阵中的污染物固定.
主要方法:
- 使用天然热带石 (NZ),改性热带石 (NaZ) 和飞灰 (FA) 的地质聚合物合成,具有不同的FT百分比 (20-50%).
- 用 10 M NaOH 溶液进行激活.
- 使用XRD,TG/DTG,无限制压力强度 (UCS) 和TCLP测试进行表征.
- 使用PHREEQC.地质化学建模.
主要成果:
- 由于尾矿的惰性性,以岩为基础的地质聚合物强度随着FT含量增加而下降.
- 基于飞灰的地质聚合物表现出更好的性能,具有更高的FT含量.
- 最高的UCS为44.3MPa,在以FA为基础的地质聚合物中达到50%的FT.
- 在基于FA的地质聚合物中,确定了最佳的摩尔比率 (Ca/Si=0.4,Si/Al=3.0,Na/Al=1.1).
结论:
- 地质聚合是一种可行的技术,用于可持续处理和重复使用铜漂浮尾矿.
- 基于飞灰的地质聚合物在结合FT方面表现出卓越的性能.
- 这种方法提供了一种废物利用和环境污染减轻的方法.
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