通过滚动和压缩生产的石墨中的电导率
Nikolai S Morozov1, Vladimir A Shulyak1, Margarita G Isaenkova2
1Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia.
Materials (Basel, Switzerland)
|January 8, 2025
概括
这项研究研究了和压如何影响柔性石墨的导电性. 优化计算显示,微菌株和二级相降低导电性,而纹理度影响异构性.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 柔性石墨薄膜 (GF) 在需要良好的电性能的各种应用中使用.
- 制造过程极大地影响了GF的微观结构和特性.
- 了解结构-属性关系对于优化GF性能至关重要.
研究的目的:
- 调查影响柔性石墨薄膜 (GF) 电导率的因素.
- 检查通过或压制生产的GF中电导率,纹理和结构之间的关系.
- 为了将纹理度和亚结构特征与电导性异质相关联.
主要方法:
- 通过制生产的GF与压制生产的GF的比较分析.
- 微观结构的表征,以评估纹理和亚结构.
- 测量和分析不同方向的电导率.
- 应用凯恩斯纹理参数用于导电率计算.
主要成果:
- 电导率受到成型过程 (制或压制) 的重大影响.
- 纹理清晰度,电导性异构性和亚结构特征之间存在相关性.
- 增加的微菌株和二次相子结构的存在被发现会降低导电性.
- 通过结合薄膜结构特征,实现了优化电导率计算.
结论:
- 形成方法批判性地确定了柔性石墨薄膜的电导率和异性质.
- 微观结构特征,包括纹理和亚结构,是GF电气性能的关键决定因素.
- 该研究为优化GF生产以满足特定导电性要求提供了一个框架.
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