温度和水蒸气含量对C/C-SiC复合材料微观结构,机械性能和腐蚀行为的影响
Yanbin Wei1, Zhiyong Ye1, Yalei Wang1
1National Key Laboratory of Science and Technology on High-Strength Structural Materials, Central South University, Changsha 410083, China.
Materials (Basel, Switzerland)
|January 8, 2025
概括
水蒸气中的氧化破坏了碳纤维增强的碳和碳化 (C/C-SiC) 复合材料. 较高的温度严重降低曲强度,并将断裂模式转向脆性,影响高温应用.
科学领域:
- 材料科学 材料科学 材料科学
- 复合材料 复合材料 复合材料
- 高温材料 高温材料
背景情况:
- 碳纤维增强的碳和碳化 (C/C-SiC) 复合材料是先进的材料.
- 了解它们在氧化环境中的行为对于结构完整性至关重要.
研究的目的:
- 为了研究C/C-SiC复合材料在水蒸气中的氧化行为.
- 为了评估氧化对微观结构和高温下柔性特性的影响.
主要方法:
- 通过化学蒸汽透 (CVI) 和反应性融透 (RMI) 制备C/C-SiC复合材料.
- 在各种温度下在水蒸气中进行氧化测试.
- 微结构分析和柔性性能测试.
主要成果:
- 氧化抵抗的顺序:陶相 > 烧解碳 (PyC) > 碳纤维 (CF).
- 表面CFs显示形形态;PyC氧化速度比CF慢.
- SiO2保护层不足;较高的温度加剧了腐蚀,降低了曲强度.
结论:
- 由于严重的CF损伤,C/C-SiC复合材料在1200°C时表现出显著的强度降解和脆性断裂.
- 在1000°C时,强度保持率高于92%表明性能良好,但在1200°C时则是一个关键极限.
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